4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl

Base Information

• Chemical Name: 4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl
• CAS No.: 947254-06-0
• Molecular Formula: C₂₀H₁₅ClN₂O₂
• Molecular Weight: 350.804
• Mol file: 947254-06-0.mol

Synonyms:

Chemical Property of 4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl

There total 1 articles about 4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(biphenyl-4-yl)-2-chloro-2-(hydroxyimino)ethan-1-one (5337-28-0) + 4-chloro-aniline (106-47-8) → 2-(biphenyl-4-yl)-N-(4-chlorophenyl)-N'-hydroxy-2-oxoacetimidamide (947254-06-0)

Guidance literature:

DOI:10.1135/cccc20071383

Reference yield: 95.0%

cadmium(II) nitrate tetrhydrate + 4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl (947254-06-0) → Cd(H2O)2(4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl(-1H))2 (947253-87-4)

Guidance literature:

With KOH; In ethanol; equiv. amt. of soln. of metal salt in EtOH added to hot soln. of ligand in EtOH; mixt. was continuously stirred; pH decreased to 3.0-3.5; equiv.amt. of soln. of KOH in EtOH added dropwise to adjust to pH value of ab out 5-6; kept at 80°C for 1 h; mixt. cooled to ambient temp.; solid filtered off; washed (hot water, EtOH); dried; elem. anal.;

DOI:10.1134/S0036023606090105

Reference yield: 93.0%

2-(biphenyl-4-yl)-N-(4-chlorophenyl)-N'-hydroxy-2-oxoacetimidamide (947254-06-0) + 3-azapentane-1,5-diamine (111-40-0,98824-35-2) → 2,2'-[iminobis(ethylenenitrilo)]bis[2-(biphenyl-4-yl)-N-(4-chlorophenyl)-N'-hydroxyacetimidamide] (1120311-39-8)

Guidance literature:

In ethanol; at 20 ℃; for 2h;

DOI:10.1135/cccc20071383

upstream raw materials:

1-(biphenyl-4-yl)-2-chloro-2-(hydroxyimino)ethan-1-one

4-chloro-aniline

Downstream raw materials:

2,2'-[iminobis(ethylenenitrilo)]bis[2-(biphenyl-4-yl)-N-(4-chlorophenyl)-N'-hydroxyacetimidamide]

Ni(H₂O)2(4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl(-1H))2

Co(H₂O)2(4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl(-1H))2

Zn(H₂O)2(4-(4-chlorophenylaminoisonitrosoacetyl)biphenyl(-1H))2