C₁₆H₂₆O₄

Base Information

• Chemical Name: C₁₆H₂₆O₄
• CAS No.: 1390618-98-0
• Molecular Formula: C₁₆H₂₆O₄
• Molecular Weight: 282.38
• Mol file: 1390618-98-0.mol

Synonyms:

Chemical Property of C₁₆H₂₆O₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₆H₂₆O₄

There total 3 articles about C₁₆H₂₆O₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

[(2S,3S)-3-pentyloxiran-2-yl]methanol (89461-51-8) + 4-Methoxybenzyl alcohol (105-13-5) → C16H26O4 (1390618-98-0)

Guidance literature:

With titanium(IV) isopropylate; In toluene; for 2h; regioselective reaction; Reflux;

DOI:10.1016/j.tetlet.2012.05.094

Reference yield:

Ethyl oct-2-enoate (2351-90-8) → C16H26O4 (1390618-98-0)

Guidance literature:

Multi-step reaction with 3 steps

1: diisobutylaluminium hydride / dichloromethane / 2 h / 25 °C

2: titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate / dichloromethane / 6 h / -20 °C

3: titanium(IV) isopropylate / toluene / 2 h / Reflux

With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; diisobutylaluminium hydride; In dichloromethane; toluene; 2: Sharpless epoxidation;

DOI:10.1016/j.tetlet.2012.05.094

Reference yield:

hexanal (66-25-1) → C16H26O4 (1390618-98-0)

Guidance literature:

Multi-step reaction with 4 steps

1: dichloromethane / 6 h / 25 °C

2: diisobutylaluminium hydride / dichloromethane / 2 h / 25 °C

3: titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate / dichloromethane / 6 h / -20 °C

4: titanium(IV) isopropylate / toluene / 2 h / Reflux

With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; diisobutylaluminium hydride; In dichloromethane; toluene; 1: Wittig reaction / 3: Sharpless epoxidation;

DOI:10.1016/j.tetlet.2012.05.094

upstream raw materials:

Ethyl oct-2-enoate

[(2S,3S)-3-pentyloxiran-2-yl]methanol

4-Methoxybenzyl alcohol

hexanal

Downstream raw materials:

(S)-2-((R)-1-((4-methoxybenzyl)oxy)hexyl)oxirane

1-methoxy-4-((((5S,6R)-5-(methoxymethoxy)undec-1-en-6-yl)oxy)methyl)benzene

(8S,9R,E)-9-(4-methoxybenzyloxy)-8-(methoxymethoxy)tetradec-4-en-3-one