[Ir(OTf)(C₆H₅)(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

Base Information

• Chemical Name: [Ir(OTf)(C₆H₅)(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]
• CAS No.: 937206-14-9
• Molecular Formula: C₄₁H₄₀F₃IrN₄O₃S
• Molecular Weight: 918.075
• Mol file: 937206-14-9.mol

Synonyms:

Chemical Property of [Ir(OTf)(C₆H₅)(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir(OTf)(C₆H₅)(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

There total 1 articles about [Ir(OTf)(C₆H₅)(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.9%

[Ir(OTf)(CH3)(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] (937206-05-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → [Ir(OTf)(C6H5)(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] (937206-14-9)

Guidance literature:

In benzene; byproducts: methane; High Pressure; (Ar); heating of Ir(4,4'-di-tert-butyldipyridyl)(OTf)(Me)(C5H4NC5H2NC6H5) at 170°C in benzene in Schlenk bomb for 6.5 h; removal of solvent under reduced pressure; crystn., redissolving in min.amt. of CH2Cl2; repptn. with pentane; elem. anal.;

DOI:10.1021/om900014h

Reference yield:

benzene-d6 (1076-43-3) + [Ir(OTf)(C6H5)(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] (937206-14-9) → [Ir(OTf)(C6D5)(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

Guidance literature:

In benzene-d6; (Ar); using Schlenk techniques; heating of Ir(Ph)(OTf)((CMe3C5H3N)2)(C5H4NC5H2NPh) in C6D6 at 170°C for 12 h;

DOI:10.1021/om900014h

Reference yield:

pyridine (110-86-1) + [Ir(OTf)(C6H5)(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] (937206-14-9) → [Ir(pyridine)(C6H5)(C5H4NC5H2NPh)(4,4'-di-tert-butyldipyridyl)](triflate) (937206-13-8)

Guidance literature:

In pyridine; dichloromethane; High Pressure; (Ar); dissolving of Ir(4,4'-di-tert-butyldipyridyl)(OTf)(Ph)(C5H4NC5H2NC6H5) in 1:1 pyridine/CH2Cl2 in Schlenk bomb; stirring for 30 min; removal of solvent under reduced pressure; crystn. from concd. CDCl3 overnight;

DOI:10.1021/om900014h

upstream raw materials:

[Ir(OTf)(CH₃)(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

benzene

Downstream raw materials:

[Ir(pyridine)(C₆H₅)(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyldipyridyl)](triflate)