Technology Process of dichloro(5,10,15,20-tetra-p-tolylporphyrinato)vanadium (IV)
There total 2 articles about dichloro(5,10,15,20-tetra-p-tolylporphyrinato)vanadium (IV) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
thionyl chloride;
In
dichloromethane;
under Ar, V-compd. dissolved in CH2Cl2, 10 equiv of SOCl2 added, maintained at room temp. with stirring for 24 h, placed in refrigerator; filtered, washed with hexane, dried; elem. anal.;
DOI:10.1039/DT9820001451
- Guidance literature:
-
In
toluene;
under Ar, V-compd. dissolved in toluene, 10 equiv of (COCl)2 added, maintained at room temp. with stirring for 12 h, placed in refrigerator; filtered, washed with hexane, dried; elem. anal.;
DOI:10.1039/DT9820001451
- Guidance literature:
-
With
aniline;
In
toluene;
byproducts: (C6H5)NH3Cl; under Ar; freshly distd. aniline slowly added to suspn. of V-complex; stirred for 12 h at room temp.; toluene and aniline removed in high vac.; chromd. (Al2O3, toluene); first fraction freed from toluene; washed (methanol and n-hexane); recrystd. (benzene/n-hexane 1:3); dried in high vac. at 80°C; elem. anal.;
