ax-Ru(CO)4(P(C₆H₅)3)

Base Information Edit

Chemical Name:ax-Ru(CO)4(P(C₆H₅)3)
CAS No.:262603-33-8
Molecular Formula:C₂₂H₁₅O₄PRu
Molecular Weight:475.402
Hs Code.:
Mol file:262603-33-8.mol

ax-Ru(CO)4(P(C<sub>6</sub>H<sub>5</sub>)3)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ax-Ru(CO)4(P(C₆H₅)3) Edit

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Technology Process of ax-Ru(CO)4(P(C₆H₅)3)

There total 23 articles about ax-Ru(CO)4(P(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 74-85-1
ethene

: 33635-52-8,262603-33-8,21192-23-4
ruthenium (CO)4(P(C₆H₅)3)

Guidance literature:: With PPh₃; In hexane; byproducts: ethylene; Irradiation (UV/VIS); according to: L. Chen, A. J. Poe, Inorg. Chem. 28 (1989) 3641; flushing suspn. of Ru-complex with ethylene, irradiation (high-pressure Hg lamp, bubbling ethylene through soln. ca. 1 h), org. ligand addn., irradiation until no ethylene formation; soln. concn. (vac.), residue chromy. (hexane/Et2O );
DOI:10.1002/hlca.19930760220

Reference yield: 34.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: (PPh3)2Pt(μ-η1:η2α,β-CH=C=CH2)-Fe(CO)Cp

: 33635-52-8,262603-33-8,21192-23-4
ruthenium (CO)4(P(C₆H₅)3)

: (PPh3)(CO)Pt(μ3-η1:η2:η2-CH=C=CH2)Ru(CO)3Fe(CO)Cp

Guidance literature:: In hexane; (Ar); at reflux temp. for 1h; hot contents filtered through a pad of Celite; solvent removed; tar dissolved (CH2Cl2); chromd. (Al2O3, hexane, THF); evapd.; crystd. (THF/hexane); elem. anal.;
DOI:10.1021/om000205g

Reference yield: 25.0%

: H₃CuRu₄*12CO*P(C₆H₅)3=H₃Ru₄(CO)12CuP(C₆H₅)3

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 205441-17-4
Ru₃(CO)11(PPh₃)

: 33635-52-8,262603-33-8,21192-23-4
ruthenium (CO)4(P(C₆H₅)3)

: H₄(ruthenium)4(carbonyl)12

: HRu₅Cu*18CO*P(C₆H₅)3=HRu₅Cu(CO)18P(C₆H₅)3

Guidance literature:: With CO; In octane; passage of CO through an octane soln. of H3Ru4(CO)12CuPPh3 at 60°C for 24 h; complex was separated from other products by column chromy.; IR, NMR, elem. anal.;
DOI:10.1039/c39870000637