{PtCl₂(NC(C₆H₄CH₃)OCH₂CH₂)2}

Base Information

• Chemical Name: {PtCl₂(NC(C₆H₄CH₃)OCH₂CH₂)2}
• CAS No.: 148684-51-9
• Molecular Formula: C₂₀H₂₂Cl₂N₂O₂Pt
• Molecular Weight: 588.393
• Mol file: 148684-51-9.mol

Synonyms:

Chemical Property of {PtCl₂(NC(C₆H₄CH₃)OCH₂CH₂)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of {PtCl₂(NC(C₆H₄CH₃)OCH₂CH₂)2}

There total 2 articles about {PtCl₂(NC(C₆H₄CH₃)OCH₂CH₂)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

cis-bis(o-tolunitrile)dichloroplatinum(II) (146143-87-5,107002-49-3) + 2-chloro-ethanol (107-07-3) → {PtCl2(NC(C6H4CH3)OCH2CH2)2} (148684-51-9,148632-23-9)

Guidance literature:

With LiC₄H₉; In tetrahydrofuran; hexane; under N2; treating a soln. of ClCH2CH2OH (excess) in THF at 0°C with LiC4H9 in hexane; addn. of 1/2 equivalent of cis-(PtCl2(NCC6H4CH3-o)2); stirring after 5 min for 10 min; warming to room temperature;; taking to dryness under reduced pressure; treating with CH3OH; filtration; washing with ether; drying under vac.; elem. anal.;;

DOI:10.1039/DT9930000959

Reference yield: 68.0%

trans-bis(o-tolunitrile)dichloroplatinum(II) (146143-87-5,107002-49-3) + 2-chloro-ethanol (107-07-3) → {PtCl2(NC(C6H4CH3)OCH2CH2)2} (148632-23-9,148684-51-9)

Guidance literature:

With LiC₄H₉; In tetrahydrofuran; hexane; under N2; treating a soln. of ClCH2CH2OH (excess) in THF at 0°C with LiC4H9 in hexane; addn. of 1/2 equivalent of trans-(PtCl2(NCC6H4CH3-o)2); pptn. after 10 min; warming to room temperature; stirring for 3 h;; filtration; washing with CH3OH, then ether; drying under vac.; elem. anal.;;

DOI:10.1039/DT9930000959

upstream raw materials:

cis-bis(o-tolunitrile)dichloroplatinum(II)

2-chloro-ethanol

trans-bis(o-tolunitrile)dichloroplatinum(II)