cis-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide

Base Information

• Chemical Name: cis-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide
• CAS No.: 57699-31-7
• Molecular Formula: C₁₈H₁₄N₂O₉
• Molecular Weight: 402.317
• Mol file: 57699-31-7.mol

Synonyms:

Chemical Property of cis-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide

There total 4 articles about cis-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitrobenzoyl cyanide (6048-20-0) → cis-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide (57699-31-7)

Guidance literature:

Multi-step reaction with 3 steps

1: HCl (gas) / diethyl ether / 1 h

2: water

3: hexamethylphosphorous triamide / benzene / 0.17 h / Heating

With hydrogenchloride; water; Hexamethylphosphorous triamide; In diethyl ether; benzene;

DOI:10.1021/jo00133a021

Reference yield:

2-(4-Nitro-phenyl)-2-oxo-acetimidic acid methyl ester → cis-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide (57699-31-7)

Guidance literature:

Multi-step reaction with 2 steps

1: water

2: hexamethylphosphorous triamide / benzene / 0.17 h / Heating

With water; Hexamethylphosphorous triamide; In benzene;

DOI:10.1021/jo00133a021

Reference yield:

methyl p-nitrophenylglyoxylate (57699-27-1) → cis-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide (57699-31-7) + trans-2,3-bis(carbomethoxy)-p,p'-dinitrostilbene oxide (81316-40-7)

Guidance literature:

With Hexamethylphosphorous triamide; In benzene; for 0.166667h; Yield given. Yields of byproduct given; Heating;

DOI:10.1021/jo00133a021

upstream raw materials:

methyl p-nitrophenylglyoxylate

4-nitrobenzoyl cyanide