1,4-anhydro-2,3-O-(S)-benzylidene-5,6-di-O-methyl-D-mannitol

Base Information

Chemical Name:1,4-anhydro-2,3-O-(S)-benzylidene-5,6-di-O-methyl-D-mannitol
CAS No.:86319-44-0
Molecular Formula:C₁₅H₂₀O₅
Molecular Weight:280.321
Hs Code.:

Synonyms:

Suppliers and Price of 1,4-anhydro-2,3-O-(S)-benzylidene-5,6-di-O-methyl-D-mannitol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,4-anhydro-2,3-O-(S)-benzylidene-5,6-di-O-methyl-D-mannitol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,4-anhydro-2,3-O-(S)-benzylidene-5,6-di-O-methyl-D-mannitol

There total 13 articles about 1,4-anhydro-2,3-O-(S)-benzylidene-5,6-di-O-methyl-D-mannitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 86319-36-0
1,4-anhydro-2,6-di-O-benzoyl-D-mannitol

: 86319-44-0,86362-56-3
1,4-anhydro-2,3-O-(R)-benzylidene-5,6-di-O-methyl-D-mannitol

Guidance literature:: Multi-step reaction with 4 steps

1: 71 percent / zinc chloride / 168 h

2: 76 percent / sodium methoxide / methanol / 1 h / Ambient temperature

3: 64 percent / acetic acid

4: 1.) sodium hydride / 1.) N,N-dimethylformamide, ice-cooling, 30 min; 2.) overnight, r.t.

With sodium methylate; sodium hydride; zinc(II) chloride; In methanol; acetic acid;
DOI:10.1016/S0008-6215(00)90952-2

Reference yield:

: 86319-36-0
1,4-anhydro-2,6-di-O-benzoyl-D-mannitol

: 86319-44-0,86362-56-3
1,4-anhydro-2,3-O-(S)-benzylidene-5,6-di-O-methyl-D-mannitol

Guidance literature:: Multi-step reaction with 5 steps

1: 71 percent / zinc chloride / 168 h

2: 76 percent / sodium methoxide / methanol / 1 h / Ambient temperature

3: 64 percent / acetic acid

4: 25 percent / toluene-p-sulphonic acid / dimethylformamide / 168 h / 37 °C

5: 1.) sodium hydride / 1.) N,N-dimethylformamide, ice-cooling, 30 min; 2.) overnight, r.t.

With sodium methylate; sodium hydride; toluene-4-sulfonic acid; zinc(II) chloride; In methanol; acetic acid; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(00)90952-2

Reference yield:

: 100-52-7
benzaldehyde

: 86319-44-0,86362-56-3
1,4-anhydro-2,3-O-(R)-benzylidene-5,6-di-O-methyl-D-mannitol

Guidance literature:: Multi-step reaction with 4 steps

1: 71 percent / zinc chloride / 168 h

2: 76 percent / sodium methoxide / methanol / 1 h / Ambient temperature

3: 64 percent / acetic acid

4: 1.) sodium hydride / 1.) N,N-dimethylformamide, ice-cooling, 30 min; 2.) overnight, r.t.

With sodium methylate; sodium hydride; zinc(II) chloride; In methanol; acetic acid;
DOI:10.1016/S0008-6215(00)90952-2