2-(Dibenzo[b,e]borinin-5(10h)-yloxy)ethanamine

Base Information

Chemical Name:2-(Dibenzo[b,e]borinin-5(10h)-yloxy)ethanamine
CAS No.:7147-07-1
Molecular Formula:C₁₅H₁₆BNO
Molecular Weight:237.109
Hs Code.:
NSC Number:54026
DSSTox Substance ID:DTXSID90288077
Wikidata:Q82024352

Synonyms:7147-07-1;2-(dibenzo[b,e]borinin-5(10h)-yloxy)ethanamine;NSC54026;DTXSID90288077;NSC-54026

Suppliers and Price of 2-(Dibenzo[b,e]borinin-5(10h)-yloxy)ethanamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 2-(Dibenzo[b,e]borinin-5(10h)-yloxy)ethanamine

Chemical Property:

Vapor Pressure:2.38E-05mmHg at 25°C
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:237.1324943
Heavy Atom Count:18
Complexity:251

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B1(C2=CC=CC=C2CC3=CC=CC=C31)OCCN

Technology Process of 2-(Dibenzo[b,e]borinin-5(10h)-yloxy)ethanamine

There total 7 articles about 2-(Dibenzo[b,e]borinin-5(10h)-yloxy)ethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 688-74-4
boric acid tributyl ester

: 2-bromo-1-(2-bromobenzyl)-4-methylbenzene

: 141-43-5
ethanolamine

: 7147-07-1
9-(2-Aminoaethoxy)-9,10-dihydro-9-boraanthracen

Guidance literature:: boric acid tributyl ester; 2-bromo-1-(2-bromobenzyl)-4-methylbenzene; With iodine; magnesium; In tetrahydrofuran; at 20 ℃; for 73h; Inert atmosphere;

ethanolamine; In ethyl acetate; at 20 ℃; Inert atmosphere;
DOI:10.1002/chem.202003319

Reference yield: 61.0%

: 1139-65-7
dichloro(N,N-diphenylamino)borane

: 141-43-5
ethanolamine

: CH₂(C₆H₄MgCl)2

: 7147-07-1
9-(2-Aminoaethoxy)-9,10-dihydro-9-boraanthracen

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; benzene; (Ar); to THF soln. of Grignard reagent was added boron compd. in benzene and react. quenched after 15 min with aq. HCl, soln. was extd. with ether, dried (Na2SO4) exts. evapd. in vac. and residual oil treated with ethanolamine; after 5 min mixt. was poured into ether/water (1:1), pptd. product was filtered off and recrystd. from EtOH;
DOI:10.1021/ja00319a032

Reference yield:

: 6630-33-7
ortho-bromobenzaldehyde

: 7147-07-1
9-(2-Aminoaethoxy)-9,10-dihydro-9-boraanthracen

Guidance literature:: Multi-step reaction with 3 steps

1.1: isopropylmagnesium chloride / tetrahydrofuran / 1.5 h / -20 °C / Inert atmosphere

1.2: 0.75 h / -20 - -15 °C / Inert atmosphere

2.1: trifluoroacetic acid / dichloromethane / 0.08 h / 0 °C

2.2: 16 h / 0 - 20 °C

3.1: iodine; magnesium / tetrahydrofuran / 73 h / 20 °C / Inert atmosphere

3.2: 20 °C / Inert atmosphere

With iodine; isopropylmagnesium chloride; magnesium; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1002/chem.202003319