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Boranamine, 1,1-dichloro-N,N-diphenyl-, also known as 1,1-dichloro-N,N-diphenylboranamine, is an organoborane compound with the chemical formula C14H14BCl2N. It is a colorless to pale yellow crystalline solid that is sensitive to air and moisture. Boranamine, 1,1-dichloro-N,N-diphenyl- is a derivative of borane, where one hydrogen atom is replaced by an amine group, and two chlorine atoms are attached to the boron atom. It is used as a reagent in organic synthesis, particularly in the formation of carbon-carbon bonds through the Suzuki-Miyaura cross-coupling reaction. Due to its sensitivity, it should be handled under an inert atmosphere and stored away from heat and light.

1139-65-7

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1139-65-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1139-65-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,3 and 9 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1139-65:
(6*1)+(5*1)+(4*3)+(3*9)+(2*6)+(1*5)=67
67 % 10 = 7
So 1139-65-7 is a valid CAS Registry Number.

1139-65-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name dichloro(N,N-diphenylamino)borane

1.2 Other means of identification

Product number -
Other names Dichlorboryl-diphenyl-amin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1139-65-7 SDS

1139-65-7Relevant academic research and scientific papers

Borole formation by 1,1-carboboration

Ge, Fang,Kehr, Gerald,Daniliuc, Constantin G.,Erker, Gerhard

supporting information, p. 68 - 71 (2014/01/23)

Bis(trimethylsilylethynyl)diphenylaminoborane was reacted with the strong Lewis acid B(C6F5)3 at ambient temperature to give the borole 9 admixed with a small amount of its thermal follow-up product 12. Compound 9 was subsequently stabilized by adduct formation with pyridine (10). Treatment of bis(trimethylsilylethynyl)phenylborane with B(C 6F5)3 gave the borole 14, which reacted with 3-hexyne to give the [4 + 2] cycloaddition product 15.

Triaminoboranes and their metallation to N-lithiotriaminoboranes

Braun, Ulrike,Habereder, Tassilo,Noeth, Heinrich,Piotrowski, Hans,Warchhold, Marcus

, p. 1132 - 1145 (2007/10/03)

In order to study the competition between deprotonation, borate formation, and B-N bond cleavage, six triaminoboranes bearing 1-3 NH functions were treated with butyllithium. The 2-anilino-1,3,2-diazaborolidine 1 was cleanly deprotonated, but the resultin

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