3-O-methylsulfonyl-D-glucose

Base Information

• Chemical Name: 3-O-methylsulfonyl-D-glucose
• CAS No.: 61135-41-9
• Molecular Formula: C₇H₁₄O₈S
• Molecular Weight: 258.249
• Mol file: 61135-41-9.mol

Synonyms:

Chemical Property of 3-O-methylsulfonyl-D-glucose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-O-methylsulfonyl-D-glucose

There total 2 articles about 3-O-methylsulfonyl-D-glucose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2,5,6-di-O-isopropylidene-3-O-methylsulfonyl-α-D-glucofuranose (5450-26-0) → 3-O-methylsulfonyl-D-glucose (61135-45-3) + 3-O-methylsulfonyl-D-glucose (61135-41-9)

Guidance literature:

With Amberlite IR 120 (H⁺) ion exchange resin; water; at 60 ℃; for 8h; Title compound not separated from byproducts;

DOI:10.1016/S0008-6215(96)00328-X

Reference yield:

→ 3-Mesyl-D-glucose (61135-41-9,61135-45-3)

Guidance literature:

1.2,5.6-Diisopropyliden-3-mesyl-D-glucofuranose;

DOI:10.1002/hlca.19600430626

Reference yield:

3-O-methylsulfonyl-D-glucose (61135-41-9) + trityl chloride (76-83-5) → Methanesulfonic acid (2S,3R,4S,5R,6R)-2,3,5-trihydroxy-6-trityloxymethyl-tetrahydro-pyran-4-yl ester

Guidance literature:

With pyridine;

DOI:10.1139/v75-303

upstream raw materials:

1,2,5,6-di-O-isopropylidene-3-O-methylsulfonyl-α-D-glucofuranose

Refernces