1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose

Base Information

Chemical Name:1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose
CAS No.:5450-26-0
Molecular Formula:C13H22 O8 S
Molecular Weight:338.379
Hs Code.:
European Community (EC) Number:226-675-3
Mol file:5450-26-0.mol

Synonyms:5450-26-0;1,2:5,6-Di-O-isopropylidene-3-O-(methylsulfonyl)-alpha-D-glucofuranose;C13H22O8S;1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose;C13-H22-O8-S;SCHEMBL2757717;W-203055

Suppliers and Price of 1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose
25g
$ 342.00

Crysdot
(3AR,5R,6S,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ylmethanesulfonate 97%
500g
$ 904.00

Chemenu
(3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ylmethanesulfonate 97%
500g
$ 853.00

Biosynth Carbosynth
1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose
250 g
$ 157.50

Biosynth Carbosynth
1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose
100 g
$ 88.00

Biosynth Carbosynth
1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose
500 g
$ 280.00

American Custom Chemicals Corporation
3-O-METHANESULPHONYL-1,2,5,6-DI-O-ISOPROPYLIDENE-D-GLUCOFURANOSE 95.00%
5G
$ 157.50

Total 22 raw suppliers

Chemical Property of 1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose

Chemical Property:

Appearance/Colour:off-white powder powder
Vapor Pressure:8.71E-08mmHg at 25°C
Melting Point:79-81 ºC
Refractive Index:1.52
Boiling Point:447.7 °C at 760 mmHg
Flash Point:224.5 °C
PSA：97.90000
Density:1.36 g/cm³
LogP:1.43990
Storage Temp.:0-6°C
XLogP3:0.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:3
Exact Mass:338.10353883
Heavy Atom Count:22
Complexity:537

Purity/Quality:

99%, ^*data from raw suppliers

1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(OCC(O1)C2C(C3C(O2)OC(O3)(C)C)OS(=O)(=O)C)C
Isomeric SMILES:CC1(OCC(O1)[C@@H]2[C@@H]([C@@H]3[C@H](O2)OC(O3)(C)C)OS(=O)(=O)C)C

Technology Process of 1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose

There total 3 articles about 1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 124-63-0
methanesulfonyl chloride

: 582-52-5
1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

: 5450-26-0
1,2,5,6-di-O-isopropylidene-3-O-methylsulfonyl-α-D-glucofuranose

Guidance literature:: With pyridine; In dichloromethane; for 2h;
DOI:10.1055/s-1982-29687

Reference yield:

: 2280-44-6
D-Glucose

: 5450-26-0
1,2,5,6-di-O-isopropylidene-3-O-methylsulfonyl-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / ZnCl₂, H₃PO₄

2: DMAP, Et₃N / CH₂Cl₂

With dmap; phosphoric acid; triethylamine; zinc(II) chloride; In dichloromethane;
DOI:10.1016/S0040-4039(00)73458-7