2-Methylpropyl diazoacetate

Base Information

Chemical Name:2-Methylpropyl diazoacetate
CAS No.:50639-30-0
Molecular Formula:C6H10 N2 O2
Molecular Weight:142.158
Hs Code.:
Nikkaji Number:J1.359.865G

Synonyms:50639-30-0;isobutyl diazoacetate;2-Methylpropyl diazoacetate;Acetic acid, diazo-, 2-methylpropyl ester

Suppliers and Price of 2-Methylpropyl diazoacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 2-Methylpropyl diazoacetate

Chemical Property:

XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:142.074227566
Heavy Atom Count:10
Complexity:159

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)COC(=O)C=[N+]=[N-]

Technology Process of 2-Methylpropyl diazoacetate

There total 6 articles about 2-Methylpropyl diazoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 59956-48-8
isobutyl 2-bromoacetate

: 50639-30-0
isobutyl 2-diazoacetate

Guidance literature:: With N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 0 - 20 ℃; for 0.5h;

Reference yield: 52.0%

: 78-83-1
2-methyl-propan-1-ol

: 14661-69-9
p-toluenesulfonylhydrazone glyoxylic acid chloride

: 50639-30-0
isobutyl 2-diazoacetate

Guidance literature:: 2-methyl-propan-1-ol; p-toluenesulfonylhydrazone glyoxylic acid chloride; With N,N-dimethyl-aniline; In dichloromethane; at 23 ℃; for 1h;

With triethylamine; In dichloromethane; at 23 ℃; for 0.5h;
DOI:10.1021/acs.orglett.7b01095

Reference yield:

: 57053-69-7
glycine isobutyl ester; hydrochloride

: 50639-30-0
isobutyl 2-diazoacetate

Guidance literature:: With sulfuric acid; sodium nitrite; In dichloromethane; water; at -10 ℃; Inert atmosphere;
DOI:10.1134/S1070363212100088