Technology Process of Gallium, tris[bis(1,1-dimethylethyl)phosphino]-
There total 1 articles about Gallium, tris[bis(1,1-dimethylethyl)phosphino]- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
tetrahydrofuran; toluene;
byproducts: HP(C(CH3)3)2, P2(C(CH3)3)4; LiP(C(CH3)3)2 suspended in toluene, cooled to -78 °C, GaBr soln. in 3:1 toluene/THF added dropwise, mixt. stirred, warmed to room temp. over 6 h, soln. heated to 50 °C for 1 h under reduced pressure; soln. filtered, solvent removed (vac.), residue redissolved (toluene), filtered, toluene extract stored at 7 °C for crystallization for several weeks;
DOI:10.1002/anie.200250461
- Guidance literature:
-
With
trioctylamine;
In
neat (no solvent, solid phase);
Ga(PtBu2)3 was injected into trioctylamine at 330°C, 72 h; quenched with cold toluene, treated with MeOH, centrifuged;
DOI:10.1021/ja027575b
- Guidance literature:
-
With
trioctylamine; hexadecylamine;
In
neat (no solvent, solid phase);
Ga(PtBu2)3 was injected into mixt. of trioctylamine and hexadecylamine at 330°C, 72 h; quenched with cold toluene, treated with MeOH, centrifuged;
DOI:10.1021/ja027575b
