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(+/-)-7-Methylhexahelicen

Base Information Edit
  • Chemical Name:(+/-)-7-Methylhexahelicen
  • CAS No.:33835-51-7
  • Molecular Formula:C27H18
  • Molecular Weight:342.44
  • Hs Code.:
  • Mol file:33835-51-7.mol
(+/-)-7-Methylhexahelicen

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Chemical Property of (+/-)-7-Methylhexahelicen Edit
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Technology Process of (+/-)-7-Methylhexahelicen

There total 13 articles about (+/-)-7-Methylhexahelicen which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With platinum(II) chloride; In toluene; at 100 ℃; Inert atmosphere;
DOI:10.1002/chem.201603058
Guidance literature:
Multi-step reaction with 10 steps
1.1: potassium carbonate / acetone / 72 h / 80 °C
2.1: 0.5 h / Reflux
3.1: hydrogenchloride / water; diethyl ether; methanol / 0.5 h
4.1: pyridine / dichloromethane / 1 h / 0 °C
5.1: chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I) / dichloromethane; 1,2-dichloro-benzene / 0.67 h / Reflux; Inert atmosphere
6.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C
6.2: 2 h / -78 - 20 °C
6.3: 20 °C
7.1: potassium phosphate; palladium diacetate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / water; toluene / Inert atmosphere; Reflux
8.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / chlorobenzene / 2 h / 120 °C
9.1: potassium carbonate
10.1: platinum(II) chloride / toluene / 100 °C / Inert atmosphere
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; pyridine; hydrogenchloride; potassium phosphate; n-butyllithium; chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I); palladium diacetate; potassium carbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; platinum(II) chloride; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; water; chlorobenzene; 1,2-dichloro-benzene; acetone; toluene; 2.1: |Claisen Rearrangement / 7.1: |Suzuki Coupling;
DOI:10.1002/chem.201603058
Guidance literature:
Multi-step reaction with 8 steps
1.1: 0.5 h / Reflux
1.2: 0.5 h
2.1: pyridine / dichloromethane / 1 h / 0 °C
3.1: chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I) / dichloromethane; 1,2-dichloro-benzene / 0.67 h / Reflux; Inert atmosphere
4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C
4.2: 2 h / -78 - 20 °C
4.3: 20 °C
5.1: potassium phosphate; palladium diacetate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / water; toluene / Inert atmosphere; Reflux
6.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / chlorobenzene / 2 h / 120 °C
7.1: potassium carbonate
8.1: platinum(II) chloride / toluene / 100 °C / Inert atmosphere
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; pyridine; potassium phosphate; n-butyllithium; chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I); palladium diacetate; potassium carbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; platinum(II) chloride; In tetrahydrofuran; hexane; dichloromethane; water; chlorobenzene; 1,2-dichloro-benzene; toluene; 5.1: |Suzuki Coupling;
DOI:10.1002/chem.201603058
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