(E)-N-[(Z)-3-tricyclo[2.2.1.02,6]heptanylideneamino]tricyclo[2.2.1.02,6]heptan-3-imine

Base Information

• Chemical Name: (E)-N-[(Z)-3-tricyclo[2.2.1.02,6]heptanylideneamino]tricyclo[2.2.1.02,6]heptan-3-imine
• CAS No.: 93045-13-7
• Molecular Formula: C₁₄H₁₆N₂
• Molecular Weight: 212.294
• NSC Number: 122987
• DSSTox Substance ID: DTXSID30422397
• ChEMBL ID: CHEMBL4296951
• Mol file: 93045-13-7.mol

Synonyms:MLS002707276;93045-13-7;CHEMBL4296951;DTXSID30422397;NSC122987;NSC-122987

Chemical Property of (E)-N-[(Z)-3-tricyclo[2.2.1.02,6]heptanylideneamino]tricyclo[2.2.1.02,6]heptan-3-imine

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 212.131348519
• Heavy Atom Count: 16
• Complexity: 409

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1C2CC3C1C3C2=NN=C4C5CC6C4C6C5
• Isomeric SMILES: C1C\2CC3C1C3/C2=N/N=C\4/C5CC6C4C6C5

Technology Process of (E)-N-[(Z)-3-tricyclo[2.2.1.02,6]heptanylideneamino]tricyclo[2.2.1.02,6]heptan-3-imine

There total 5 articles about (E)-N-[(Z)-3-tricyclo[2.2.1.02,6]heptanylideneamino]tricyclo[2.2.1.02,6]heptan-3-imine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nortricyclane (279-19-6) + isopropyl alcohol (67-63-0,8013-70-5) → norborn-2-ene (498-66-8) + 4-ethynylcyclopentene (330654-57-4) + 3-isopropoxy-tricyclo[2.2.1.02,6]heptane + di(3-nortricyclanylidene)hydrazine (93045-13-7)

Guidance literature:

Photolysis;

DOI:10.1021/jo005713e

Reference yield:

tricyclo<2.2.1.02.6>heptanone (695-05-6) → Nortricyclanon-azin (93045-13-7)

Guidance literature:

With hydrazine hydrate; In ethanol; acetic acid;

DOI:10.1021/jo01030a003

Reference yield:

Nortricyclyl-bromid → Nortricyclanon-azin (93045-13-7)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) DMSO, AgBF₄, (ii) Et₃N

2: N₂H₄*H₂O / ethanol; acetic acid

With hydrazine hydrate; In ethanol; acetic acid;

DOI:10.1021/jo01030a003

upstream raw materials:

tricyclo<2.2.1.0^2.6>heptanone

cyclohexane

nortricyclane

isopropyl alcohol