Technology Process of tricyclo[3.3.1.1~3,7~]decane-1,3,5,7-tetrayl tetranitrate
There total 3 articles about tricyclo[3.3.1.1~3,7~]decane-1,3,5,7-tetrayl tetranitrate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
1,3,5,7-tetrahydroxyadamantane;
With
sulfuric acid;
In
dichloromethane;
at -21 - 0 ℃;
With
nitric acid;
In
dichloromethane;
at -21 - 0 ℃;
for 0.5h;
DOI:10.1002/cplu.201700542
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: silver sulfate; sulfuric acid / 1.5 h / 50 - 80 °C
2.1: sulfuric acid / dichloromethane / -21 - 0 °C
2.2: 0.5 h / -21 - 0 °C
With
sulfuric acid; silver sulfate;
In
dichloromethane;
DOI:10.1002/cplu.201700542
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: bromine; aluminum (III) chloride / 24.5 h / 5 - 70 °C / Inert atmosphere
2.1: silver sulfate; sulfuric acid / 1.5 h / 50 - 80 °C
3.1: sulfuric acid / dichloromethane / -21 - 0 °C
3.2: 0.5 h / -21 - 0 °C
With
aluminum (III) chloride; sulfuric acid; bromine; silver sulfate;
In
dichloromethane;
DOI:10.1002/cplu.201700542
