4-(1',5'-dihydro-1'-methyl-2'H-[5,6]fullereno-C₆₀-1H-[1,9-c]pyrrol-2'-yl)benzoic acid

Base Information

• Chemical Name: 4-(1',5'-dihydro-1'-methyl-2'H-[5,6]fullereno-C₆₀-1H-[1,9-c]pyrrol-2'-yl)benzoic acid
• CAS No.: 631918-72-4
• Molecular Formula: C₇₀H₁₁NO₂
• Molecular Weight: 897.863
• Mol file: 631918-72-4.mol

Synonyms:

Chemical Property of 4-(1',5'-dihydro-1'-methyl-2'H-[5,6]fullereno-C₆₀-1H-[1,9-c]pyrrol-2'-yl)benzoic acid

Chemical Property:

• Density: 2.81±0.1 g/cm3(Predicted)

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-(1′,5′-Dihydro-1′-methyl-2′ ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Fullerene-based self-assembled monolayers for use in organic electronic devices such as inverted polymer solar cells and perovskite?polymer hybrid solar cells.

Technology Process of 4-(1',5'-dihydro-1'-methyl-2'H-[5,6]fullereno-C₆₀-1H-[1,9-c]pyrrol-2'-yl)benzoic acid

There total 2 articles about 4-(1',5'-dihydro-1'-methyl-2'H-[5,6]fullereno-C₆₀-1H-[1,9-c]pyrrol-2'-yl)benzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

sarcosine (107-97-1,25951-24-0) + 4-Carboxybenzaldehyde (619-66-9) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) → 4-(1',5'-dihydro-1'-methyl-2'H-[5,6]fullereno-C60-1H-[1,9-c]pyrrol-2'-yl)benzoic acid (631918-72-4)

Guidance literature:

In chlorobenzene; Inert atmosphere; Reflux;

DOI:10.1039/b808004f

Reference yield: 89.0%

C71H13NO2 → 4-(1',5'-dihydro-1'-methyl-2'H-[5,6]fullereno-C60-1H-[1,9-c]pyrrol-2'-yl)benzoic acid (631918-72-4)

Guidance literature:

With sodium hydride; In toluene; at 60 ℃; for 12h;

DOI:10.1002/anie.200461174

Reference yield:

[5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide (60101-30-6) + 4-(1',5'-dihydro-1'-methyl-2'H-[5,6]fullereno-C60-1H-[1,9-c]pyrrol-2'-yl)benzoic acid (631918-72-4) → AlPor-C60

Guidance literature:

In toluene; for 12h; Reflux;

DOI:10.1021/jp911937d

upstream raw materials:

sarcosine

4-Carboxybenzaldehyde

fullerene-C₆₀

Downstream raw materials:

FcAlPorC₆₀