Tris(4-methyl-8-hydroxyquinoline)aluminum

Base Information

• Chemical Name: Tris(4-methyl-8-hydroxyquinoline)aluminum
• CAS No.: 136779-65-2
• Molecular Formula: C₃₀H₂₄AlN₃O₃
• Molecular Weight: 501.52
• Mol file: 136779-65-2.mol

Synonyms:tris(4-methyl-8-hydroxyquinoline)aluminum;14752-00-2;tris[(4-methylquinolin-8-yl)oxy]alumane

Chemical Property of Tris(4-methyl-8-hydroxyquinoline)aluminum

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 501.1633050
• Heavy Atom Count: 37
• Complexity: 650

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=C2C=CC=C(C2=NC=C1)O[Al](OC3=CC=CC4=C(C=CN=C43)C)OC5=CC=CC6=C(C=CN=C65)C

Technology Process of Tris(4-methyl-8-hydroxyquinoline)aluminum

There total 2 articles about Tris(4-methyl-8-hydroxyquinoline)aluminum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aluminum(III) sulfate + 4-methylquinolin-8-ol (3846-73-9) → aluminum(III) tris(4-methyl-8-quinolinolato) (136779-65-2,14752-00-2)

Guidance literature:

In methanol; water; at 70 ℃; for 20h;

DOI:10.1177/1747519820973601

Reference yield:

aluminium trichloride (7446-70-0) + 4-methylquinolin-8-ol (3846-73-9) → aluminum(III) tris(4-methyl-8-quinolinolato) (136779-65-2,14752-00-2)

Guidance literature:

With ammonium acetate; In water; AlCl3 was mixed with the aq. solution of the ligand buffered with ammonium acetate in a 1:3 molar ratio; recrystn. from MeOH; differential scanning calorimetry, thermal gravimetric anal.;

DOI:10.1021/ja010120m

upstream raw materials:

aluminium trichloride

4-methylquinolin-8-ol