[μ-η3(C,S,S)phenyldithiobenzoate]Fe2(CO)6

Base Information

• Chemical Name: [μ-η3(C,S,S)phenyldithiobenzoate]Fe2(CO)6
• CAS No.: 1222196-13-5
• Molecular Formula: C₁₉H₁₀Fe₂O₆S₂
• Molecular Weight: 510.111
• Mol file: 1222196-13-5.mol

Synonyms:

Chemical Property of [μ-η3(C,S,S)phenyldithiobenzoate]Fe2(CO)6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [μ-η3(C,S,S)phenyldithiobenzoate]Fe2(CO)6

There total 4 articles about [μ-η3(C,S,S)phenyldithiobenzoate]Fe2(CO)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

triiron dodecarbonyl (17685-52-8) + phenyl dithiobenzoate (949-00-8) → Fe3(CO)9(μ-S)2 + {PhSFe(CO)3}2 (15634-63-6) + [μ-η3(C,S,S)phenyldithiobenzoate]Fe2(CO)6 (1222196-13-5) + [Fe2(μ-S2C2Ph2)(CO)6] (12096-77-4,14406-62-3,14875-43-5)

Guidance literature:

In toluene; Fe3(CO)12 (1.0 mmol) was added to PhCS2Ph (1.0 mmol) in dry toluene; themixt. was heated at 20-55°C for 1-72 h in the dark and under nit rogen; various product ratio for various conditions; filtration, distn. of solvent and chromatography;

DOI:10.1016/j.jorganchem.2010.01.005

Reference yield: 47.0%

triiron dodecarbonyl (17685-52-8) + phenyl dithiobenzoate (949-00-8) → {PhSFe(CO)3}2 (15634-63-6) + [μ-η3(C,S,S)phenyldithiobenzoate]Fe2(CO)6 (1222196-13-5) + [Fe2(μ-S2C2Ph2)(CO)6] (12096-77-4,14406-62-3,14875-43-5)

Guidance literature:

In acetone; Fe3(CO)12 reacted with PhCS2Ph (1.0 mmol) in acetone at 20-55°C with ultrasonic activation for 4 h; chromatography;

DOI:10.1016/j.jorganchem.2010.01.005

Reference yield: 30.0%

diiron nonacarbonyl (15321-51-4) + phenyl dithiobenzoate (949-00-8) → [μ-η3(C,S,S)phenyldithiobenzoate]Fe2(CO)6 (1222196-13-5) + [Fe2(μ-S2C2Ph2)(CO)6] (12096-77-4,14406-62-3,14875-43-5)

Guidance literature:

In acetone; Fe2(CO)9 reacted with PhCS2Ph in acetone at 55.degrees.C for 1 h; cryst. from ethanol; elem. anal.;

DOI:10.1016/j.jorganchem.2010.01.005

upstream raw materials:

triiron dodecarbonyl

phenyl dithiobenzoate

diiron nonacarbonyl