(η4-buta-1,3-diene)carbonyl(trimethoxyphosphine)(triphenylphosphine)iron

Base Information

• Chemical Name: (η4-buta-1,3-diene)carbonyl(trimethoxyphosphine)(triphenylphosphine)iron
• CAS No.: 127454-69-7
• Molecular Formula: C₂₆H₃₀FeO₄P₂
• Molecular Weight: 524.316
• Mol file: 127454-69-7.mol

Synonyms:

Chemical Property of (η4-buta-1,3-diene)carbonyl(trimethoxyphosphine)(triphenylphosphine)iron

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (η4-buta-1,3-diene)carbonyl(trimethoxyphosphine)(triphenylphosphine)iron

There total 1 articles about (η4-buta-1,3-diene)carbonyl(trimethoxyphosphine)(triphenylphosphine)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

(η4-buta-1,3-diene)dicarbonyl(triphenylphosphine)iron (15748-39-7) + phosphorous acid trimethyl ester (121-45-9) → (η4-buta-1,3-diene)carbonyl(trimethoxyphosphine)(triphenylphosphine)iron (127454-69-7)

Guidance literature:

In benzene; Irradiation (UV/VIS); UV irradn. of a benzene soln. of dicarbonyl complex in the presence of the phosphorus ligand (25°C, inert atmosphere). React. monitored by TLC.; Filtn. of soln., removal of solvent under reduced pressure, and chromy. of resulting oily residue on silica gel with hexane/Et2O as eluent. Pure compd. obtained after removal of solvent.;

DOI:10.1002/hlca.19890720803

upstream raw materials:

(η4-buta-1,3-diene)dicarbonyl(triphenylphosphine)iron

phosphorous acid trimethyl ester