RuClH(η2-C2H4)(PCy3)2

Base Information

• Chemical Name: RuClH(η2-C2H4)(PCy3)2
• CAS No.: 541539-99-5
• Molecular Formula: C₃₈H₇₁ClP₂Ru
• Molecular Weight: 726.452
• Mol file: 541539-99-5.mol

Synonyms:

Chemical Property of RuClH(η2-C2H4)(PCy3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuClH(η2-C2H4)(PCy3)2

There total 4 articles about RuClH(η2-C2H4)(PCy3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethylmonochlorosilane (1066-35-9) + RuHCl(H2)(PCy3)2 (315675-18-4,133779-04-1) + ethene (74-85-1) → RuClH(η2-C2H4)(PCy3)2 (541539-99-5)

Guidance literature:

In ⁽²⁾H₈-toluene; 1) 1 equiv. of Si compd., 2) saturated with ethylene;

DOI:10.1039/b210552g

Reference yield:

[RuCl(SiMe2Cl)(η2-H2)(PCy3)2] + ethene (74-85-1) → RuClH(η2-C2H4)(PCy3)2 (541539-99-5)

Guidance literature:

In tetrahydrofuran-d8; byproducts: ethane, chlorodimethylvinylsilane, chloroethyldimethylsilane; (under Ar, Schlenk); C2H4 bubbled through soln. of Ru-complex in C7D8; monitored by NMR;

DOI:10.1021/om700295g

Reference yield:

dimethylmonochlorosilane (1066-35-9) + RuH2(H2)2(tricyclohexylphosphine)2 (112320-11-3) + ethene (74-85-1) → RuClH(η2-C2H4)(PCy3)2 (541539-99-5) + [(Cl(CH3)2Si)RuH(P(C6H11)3)2(C2H4)]

Guidance literature:

In ⁽²⁾H₈-toluene; 1) 2 or 10 equiv. of Si compd., 2) saturated with ethylene; not isolated, detected by NMR;

DOI:10.1039/b210552g

upstream raw materials:

dimethylmonochlorosilane

RuH₂(H₂)2(tricyclohexylphosphine)2

ethene

RuHCl(H₂)(PCy₃)2

Refernces

• 1、 Lachaize, Sebastien,Caballero, Ana,Vendier, Laure,Sabo-Etienne, Sylviane. "Activation of chlorosilanes at ruthenium: A route to silyl σ-dihydrogen complexes". . p. 3713 - 3721. Retrieved 2008/10/09.