n-Hydroxy-10-nitrosophenanthren-9-amine

Base Information

• Chemical Name: n-Hydroxy-10-nitrosophenanthren-9-amine
• CAS No.: 14090-76-7
• Molecular Formula: C14H10N2O2
• Molecular Weight: 238.246
• European Community (EC) Number: 661-579-9
• NSC Number: 404733,80190
• DSSTox Substance ID: DTXSID20292066
• Nikkaji Number: J3.527.253D
• Wikidata: Q82030209
• Mol file: 14090-76-7.mol

Synonyms:14090-76-7;PHENANTHRENEQUINONE DIOXIME;n-hydroxy-10-nitrosophenanthren-9-amine;NSC80190;NCIOpen2_004292;9,10-phenanthrenedionedioxime;SCHEMBL17503329;SCHEMBL17546590;DTXSID20292066;NSC-80190;NSC404733;AKOS003619028;NSC-404733;7463-79-8

Chemical Property of n-Hydroxy-10-nitrosophenanthren-9-amine

Chemical Property:

• Vapor Pressure: 5E-11mmHg at 25°C
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 238.074227566
• Heavy Atom Count: 18
• Complexity: 310

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3C(=C2NO)N=O

Technology Process of n-Hydroxy-10-nitrosophenanthren-9-amine

There total 4 articles about n-Hydroxy-10-nitrosophenanthren-9-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

9,10-phenanthrenequinone (84-11-7) → phenanthrene-9,10-dione dioxime (14090-76-7)

Guidance literature:

With pyridine; hydroxylamine hydrochloride; In ethanol; for 22h; Reflux;

DOI:10.1021/acs.inorgchem.8b02495

Reference yield: 85.0%

1,10-phenanthroline-5,6-dione (27318-90-7) → phenanthrene-9,10-dione dioxime (14090-76-7)

Guidance literature:

With hydroxylamine hydrochloride; sodium carbonate; In ethanol; for 5h; Reflux;

Reference yield:

1,10-Phenanthroline (66-71-7) → phenanthrene-9,10-dione dioxime (14090-76-7)

Guidance literature:

Multi-step reaction with 2 steps

1: sulfuric acid; potassium bromide; nitric acid / 3 h / 90 °C / Reflux

2: sodium carbonate; hydroxylamine hydrochloride / ethanol / 5 h / Reflux

With sulfuric acid; hydroxylamine hydrochloride; nitric acid; sodium carbonate; potassium bromide; In ethanol;

upstream raw materials:

9,10-phenanthrenequinone

ethanol

1,10-phenanthroline-5,6-dione

1,10-Phenanthroline

Downstream raw materials:

9,10-diaminophenanthrene

3-phenyl-3H-phenanthro[9,10-c][1,2,5]oxadiazine 4-oxide

C₂₆H₁₈GeN₂O₂

phenanthrene-9,10-diamine hydrochloride