9,10-Phenanthrenediamine

Base Information

• Chemical Name: 9,10-Phenanthrenediamine
• CAS No.: 53348-04-2
• Molecular Formula: C14H12N2
• Molecular Weight: 208.263
• Hs Code.: 2921590090
• European Community (EC) Number: 258-490-9
• NSC Number: 80191
• DSSTox Substance ID: DTXSID30201508
• Nikkaji Number: J2.816.924H,J89.772H
• Wikidata: Q72462981
• Mol file: 53348-04-2.mol

Synonyms:phenanthrene-9,10-diamine;53348-04-2;9,10-Diaminophenanthrene;9,10-Phenanthrenediamine;EINECS 258-490-9;NSC80191;BIDD:GT0597;SCHEMBL743050;DTXSID30201508;9,10-Diaminophenanthrene, 97%;AMY33525;MFCD00001178;NSC 80191;NSC-80191;AKOS015899769;CS-W008462;DS-6624;FT-0640153;C75500;(9,10-Dihydro-9,10-diaminophenanthrene-9,10-diyl)radical

Chemical Property of 9,10-Phenanthrenediamine

Chemical Property:

• Vapor Pressure: 1.47E-08mmHg at 25°C
• Melting Point: 164-166 °C(lit.)
• Refractive Index: 1.816
• Boiling Point: 457.6 °C at 760 mmHg
• PKA: 5.15±0.30(Predicted)
• Flash Point: 276.6 °C
• PSA: 52.04000
• Density: 1.283g/cm³
• LogP: 4.31980
• Storage Temp.: 2-8°C
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 208.100048391
• Heavy Atom Count: 16
• Complexity: 227

Purity/Quality:

99% ^*data from raw suppliers

9,10Diaminophenanthrene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3C(=C2N)N

Technology Process of 9,10-Phenanthrenediamine

There total 4 articles about 9,10-Phenanthrenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9,10‐dibromophenanthrene (15810-15-8) → 9,10-diaminophenanthrene (53348-04-2)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; potassium tert-butylate; ammonia; In water; toluene; for 6h; Reflux;

Reference yield:

phenanthrene-9,10-dione dioxime (14090-76-7) → 9,10-diaminophenanthrene (53348-04-2)

Guidance literature:

With hydrogenchloride; ethanol; tin(ll) chloride;

Reference yield:

→ 9,10-diaminophenanthrene (53348-04-2)

Guidance literature:

With tetrahydrofuran; lithium aluminium tetrahydride; diethyl ether;

upstream raw materials:

phenanthrene-9,10-dione dioxime

hydrogenchloride

9,10‐dibromophenanthrene

Downstream raw materials:

phenanthro[9,10-g]pteridine-11,13(10H,12H)-dione

2,3-diphenyldibenzoquinoxaline

N,N,N',N'-tetrakis(4-biphenylyl)-9,10-phenanthrylenediamine

benzyltriphenylphosphonium tetrachloro(phenanthrene-9,10-diamine)chromate(III)