[N,o-C-(N-benzilidenebenzylaminato)]hydrido(benzylamine)bis(triphenylphosphine)iridium(III) hexafluorophosphate

Base Information

• Chemical Name: [N,o-C-(N-benzilidenebenzylaminato)]hydrido(benzylamine)bis(triphenylphosphine)iridium(III) hexafluorophosphate
• CAS No.: 754229-35-1
• Molecular Formula: C₅₇H₅₂IrN₂P₂*F₆P
• Molecular Weight: 1164.18
• Mol file: 754229-35-1.mol

Synonyms:

Chemical Property of [N,o-C-(N-benzilidenebenzylaminato)]hydrido(benzylamine)bis(triphenylphosphine)iridium(III) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [N,o-C-(N-benzilidenebenzylaminato)]hydrido(benzylamine)bis(triphenylphosphine)iridium(III) hexafluorophosphate

There total 1 articles about [N,o-C-(N-benzilidenebenzylaminato)]hydrido(benzylamine)bis(triphenylphosphine)iridium(III) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

(η4-1,5-cyclooctadiene)bis(triphenylphosphine)iridium hexafluorophosphate (61817-47-8) + hydrogen (1333-74-0) + N-benzylidene benzylamine (780-25-6) → [N,o-C-(N-benzilidenebenzylaminato)]hydrido(benzylamine)bis(triphenylphosphine)iridium(III) hexafluorophosphate (754229-35-1)

Guidance literature:

In methanol; suspn. (Ir(cod)(PPh3)2)PF6 in MeOH under 1 atm H2 was stirred at 20°C for 1 h, PhCH2N=CHPh was added and stirred for 48 h under Ar atm.; ppt. was washed with Et2O and dried in vacuo; elem. anal.;

DOI:10.1023/B:RUCB.0000019891.73897.e4

upstream raw materials:

(η4-1,5-cyclooctadiene)bis(triphenylphosphine)iridium hexafluorophosphate

hydrogen

N-benzylidene benzylamine