ax-Ru(CO)4(P(cy)3)

Base Information

• Chemical Name: ax-Ru(CO)4(P(cy)3)
• CAS No.: 121808-99-9
• Molecular Formula: C₂₂H₃₃O₄PRu
• Molecular Weight: 493.545
• Mol file: 121808-99-9.mol

Synonyms:

Chemical Property of ax-Ru(CO)4(P(cy)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ax-Ru(CO)4(P(cy)3)

There total 2 articles about ax-Ru(CO)4(P(cy)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + ethene (74-85-1) + tricyclohexylphosphine (2622-14-2) → ax-Ru(CO)4(P(cy)3) (121808-99-9)

Guidance literature:

In n-heptane; Irradiation (UV/VIS); photolysis of Ru3(CO)12 under an atmosphere of ethylene (5 min, room temp.) according Johnson, Lewis, Twigg, J. Organomet. Chem., 1974, 67, C75-C76; addn. of ligand; 5-10 min; quantitative conversion;;

Reference yield:

tetracarbonyl(η2-ethene)ruthenium (364329-15-7,52621-15-5) + tricyclohexylphosphine (2622-14-2) → ax-Ru(CO)4(P(cy)3) (121808-99-9)

Guidance literature:

In n-heptane; byproducts: C2H4; ambient temp.; mixing pre-thermostated components solns., in presence of ethene excess; monitoring by IR and UV spectroscopy; Kinetics;

DOI:10.1016/0020-1693(95)04560-0

Reference yield:

ax-Ru(CO)4(P(cy)3) (121808-99-9) + tricyclohexylphosphine (2622-14-2) → Ru(CO)3(P(c-Hex)3)2 (16592-00-0)

Guidance literature:

In n-heptane; 40,0, 50.0, 55.0, 60.0 °C;; Kinetics;

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

ethene

tricyclohexylphosphine

tetracarbonyl(η2-ethene)ruthenium

Downstream raw materials:

Ru(CO)3(P(c-Hex)3)2