cis-dicarbonyl-cis-dichlorido-trans-bis(triphenylphosphine-κP)iridium(III) tetrafluoridoborate

Base Information

• Chemical Name: cis-dicarbonyl-cis-dichlorido-trans-bis(triphenylphosphine-κP)iridium(III) tetrafluoridoborate
• CAS No.: 1030019-19-2
• Molecular Formula: BF₄*C₃₈H₃₀Cl₂IrO₂P₂
• Molecular Weight: 930.533
• Mol file: 1030019-19-2.mol

Synonyms:

Chemical Property of cis-dicarbonyl-cis-dichlorido-trans-bis(triphenylphosphine-κP)iridium(III) tetrafluoridoborate

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of cis-dicarbonyl-cis-dichlorido-trans-bis(triphenylphosphine-κP)iridium(III) tetrafluoridoborate

There total 1 articles about cis-dicarbonyl-cis-dichlorido-trans-bis(triphenylphosphine-κP)iridium(III) tetrafluoridoborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

Carbonyl fluoride (353-50-4) + bis(triphenylphosphine)(cycloocta-1,5-diene)iridium(I) tetrafluoroborate (38834-40-1) + dichloromethane (75-09-2) → cis-dicarbonyl-cis-dichlorido-trans-bis(triphenylphosphine-κP)iridium(III) tetrafluoridoborate (1030019-19-2)

Guidance literature:

In dichloromethane; Ir-compd. dissolved in CH2Cl2, cooled to 195 K, placed under 1100 Torr of COF2, warmed to room temp., stirred for 3 d; volatiles removed in vac., washed twice with cold THF, decanted at 298 K;

DOI:10.1107/S0108270107025358

upstream raw materials:

Carbonyl fluoride

bis(triphenylphosphine)(cycloocta-1,5-diene)iridium(I) tetrafluoroborate

dichloromethane