(2-aminoethyl)butylphenylphosphine

Base Information

• Chemical Name: (2-aminoethyl)butylphenylphosphine
• CAS No.: 67747-69-7
• Molecular Formula: C₁₂H₂₀NP
• Molecular Weight: 209.271
• Mol file: 67747-69-7.mol

Synonyms:

Chemical Property of (2-aminoethyl)butylphenylphosphine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-aminoethyl)butylphenylphosphine

There total 1 articles about (2-aminoethyl)butylphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-butane (109-65-9) + (2-aminoethyl)diphenylphosphane (4848-43-5) → (2-aminoethyl)butylphenylphosphine (67747-67-5,67747-68-6,67747-69-7)

Guidance literature:

With sodium; Yield given. Multistep reaction; 1.) liq. NH₃, 2 h, 2.) liq. NH₃;

DOI:10.1246/bcsj.53.3715

Reference yield:

cis-dichlorobis(ethylenediamine)cobalt(III) chloride + (2-aminoethyl)butylphenylphosphine (67747-67-5,67747-68-6,67747-69-7) + sodium bromide (7647-15-6) → Λ-[Co(en)2(S-ebpp)]3+ (717089-68-4) + [Co(en)2(rac-ebpp)]Br3*2H2O + Λ-[Co(en)2(S-ebpp)]Br3*4NaBr

Guidance literature:

In N,N-dimethyl-formamide; a soln. of ligand and complex was stirred overnight at room temperature, N2 atm; pouring into water, filtration, column chromy. (Sephadex C-25, aq. Na2SO4), evapn., extn. (MeOH), column chromy (Sephadex C-25, aq. sodium (+)-tartratoantimonate(III)), column chromy. (SP-Sephadex C-25, aq. NaBr), concn.; elem. anal.;

DOI:10.1246/bcsj.54.2683

upstream raw materials:

1-bromo-butane

(2-aminoethyl)diphenylphosphane

Downstream raw materials:

Λ-[Co(en)2(S-ebpp)]3+