Methanimidamide, N,N'-bis(4-methoxyphenyl)-, (E)-

Base Information

• Chemical Name: Methanimidamide, N,N'-bis(4-methoxyphenyl)-, (E)-
• CAS No.: 141417-87-0
• Molecular Formula: C₁₅H₁₆N₂O₂
• Molecular Weight: 256.304
• Mol file: 141417-87-0.mol

Synonyms:

Chemical Property of Methanimidamide, N,N'-bis(4-methoxyphenyl)-, (E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanimidamide, N,N'-bis(4-methoxyphenyl)-, (E)-

There total 27 articles about Methanimidamide, N,N'-bis(4-methoxyphenyl)-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100%

C7H7NO(2-)*2Br(1-)*2Mg(2+) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → N,N'-bis(4-methoxyphenyl)iminoformamide (1152-75-6,141417-87-0)

Guidance literature:

In tetrahydrofuran; at 10 ℃; for 1h;

DOI:10.1246/cl.1991.1965

Reference yield: 95%

4-methoxy-aniline (104-94-9) + orthoformic acid triethyl ester (122-51-0) → N,N'-bis(4-methoxyphenyl)iminoformamide (1152-75-6,141417-87-0)

Guidance literature:

With β‐cyclodextrin; In ethanol; water; at 20 ℃; for 10h; Solvent; Time; Catalytic behavior; Green chemistry;

DOI:10.1016/j.cclet.2012.08.003

Reference yield: 94.3%

4-methoxy-aniline (104-94-9) + acetic acid (64-19-7,77671-22-8) → N,N'-bis(4-methoxyphenyl)iminoformamide (1152-75-6,141417-87-0)

Guidance literature:

With orthoformic acid triethyl ester; at 140 ℃; for 24h;

DOI:10.1021/acs.joc.8b00151

upstream raw materials:

4-methoxy-aniline

orthoformic acid triethyl ester

4-methoxyformanilide

dimethyl sulfate

Downstream raw materials:

N-[2-(1-ethyl-1H-[2]quinolyliden)-ethyliden]-p-anisidine; hydriodide

1,5-Dihydro-5-(4-methoxyphenyl)-4H-pyrazolo<3,4-d>pyrimidin-4-one

3,5,6-trichloro-2-(4-methoxyphenylamino)-1,4-benzoquinone

Mo₂(N,N′-di(p-anisyl)formamidinate)₃(O₂CCH₃)

Refernces

• 1、 Hsu, Chia-Wei,Iniguez, Sarah J.,Johnson, Brittany J.,Mankad, Neal P.,Rathnayaka, Suresh C.. "Impact of Electronic and Steric Changes of Ligands on the Assembly, Stability, and Redox Activity of Cu4(μ4-S) Model Compounds of the CuZ Active Site of Nitrous Oxide Reductase (N2OR)". . p. 6496 - 6507. Retrieved 2020/05/01.
• 2、 Mazloumi,Shirini,Goli-Jolodar,Seddighi. "Nanoporous TiO2 containing an ionic liquid bridge as an efficient and reusable catalyst for the synthesis of: N, N ′-diarylformamidines, benzoxazoles, benzothiazoles and benzimidazoles". . p. 5742 - 5752. Retrieved 2018/04/23.