bis-(3-methylsulfanyl-phenyl)-diazene

Base Information

• Chemical Name: bis-(3-methylsulfanyl-phenyl)-diazene
• CAS No.: 857586-90-4
• Molecular Formula: C₁₄H₁₄N₂S₂
• Molecular Weight: 274.411
• Mol file: 857586-90-4.mol

Synonyms:

Chemical Property of bis-(3-methylsulfanyl-phenyl)-diazene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis-(3-methylsulfanyl-phenyl)-diazene

There total 8 articles about bis-(3-methylsulfanyl-phenyl)-diazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-nitrobenzenediazonium (16278-29-8) → bis-(3-methylsulfanyl-phenyl)-diazene (857586-90-4)

Guidance literature:

Multi-step reaction with 5 steps

1: copper (I)-thiocyanate / -10 °C

2: ethanolic NH₃

3: aq.-ethanolic NaOH; Na₂S / Schuetteln der erhaltenen Natrium-<3-nitro-thiophenolat>-Loesung mit Dimethylsulfat und wss. NaOH unter Kuehlung

4: methanol

5: zinc; aqueous hydrogen peroxide

With methanol; sodium sulfide; sodium hydroxide; copper(I) thiocyanate; ammonia; dihydrogen peroxide; zinc;

Reference yield:

3-nitrophenyl thiocyanate (16671-77-5) → bis-(3-methylsulfanyl-phenyl)-diazene (857586-90-4)

Guidance literature:

Multi-step reaction with 4 steps

1: ethanolic NH₃

2: aq.-ethanolic NaOH; Na₂S / Schuetteln der erhaltenen Natrium-<3-nitro-thiophenolat>-Loesung mit Dimethylsulfat und wss. NaOH unter Kuehlung

3: methanol

4: zinc; aqueous hydrogen peroxide

With methanol; sodium sulfide; sodium hydroxide; ammonia; dihydrogen peroxide; zinc;

Reference yield:

bis(3-nitrophenyl) disulfide (537-91-7) → bis-(3-methylsulfanyl-phenyl)-diazene (857586-90-4)

Guidance literature:

Multi-step reaction with 3 steps

1: aq.-ethanolic NaOH; Na₂S / Schuetteln der erhaltenen Natrium-<3-nitro-thiophenolat>-Loesung mit Dimethylsulfat und wss. NaOH unter Kuehlung

2: methanol

3: zinc; aqueous hydrogen peroxide

With methanol; sodium sulfide; sodium hydroxide; dihydrogen peroxide; zinc;

upstream raw materials:

1-(methylsulfanyl)-3-nitrobenzene

bis-(3-methylsulfanyl-phenyl)-diazene-N-oxide

ethanol

sodium acetate