[Fe(CNiPr₂)(CO)3(PPh₃)]O₂CCF₃

Base Information

• Chemical Name: [Fe(CNiPr₂)(CO)3(PPh₃)]O₂CCF₃
• CAS No.: 164072-08-6
• Molecular Formula: C₂F₃O₂*C₂₈H₂₉FeNO₃P
• Molecular Weight: 627.38
• Mol file: 164072-08-6.mol

Synonyms:

Chemical Property of [Fe(CNiPr₂)(CO)3(PPh₃)]O₂CCF₃

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of [Fe(CNiPr₂)(CO)3(PPh₃)]O₂CCF₃

There total 2 articles about [Fe(CNiPr₂)(CO)3(PPh₃)]O₂CCF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + triphenylphosphine (603-35-0) + trifluoroacetic anhydride (407-25-0) + lithium diisopropyl amide (4111-54-0) → [Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3) (164072-10-0) + [Fe(CNiPr2)(CO)3(PPh3)]O2CCF3 (164072-08-6)

Guidance literature:

In diethyl ether; dichloromethane; N2-atmosphere; stirring (15 min), PPh3 addn.; petroleum ether addn., filtering, concg. (-30°C), filtering, washing (THF), petroleum ether addn. (-30°C);

DOI:10.1021/om00004a007

Reference yield: 12.5%

iron pentacarbonyl (13463-40-6,71564-23-3,37220-42-1) + triphenylphosphine (603-35-0) + trifluoroacetic anhydride (407-25-0) + lithium diisopropyl amide (4111-54-0) → [Fe(η2-OCNiPr2)(CO)2(PPh3)2](O2CCF3) (164072-10-0) + [Fe(CNiPr2)(CO)3(PPh3)]O2CCF3 (164072-08-6)

Guidance literature:

In diethyl ether; under N2 atm. to soln. (Fe(CO)5) in Et2O LDA was added, react. mixt. was cooled in dry ice/propanone bath, (CF3CO)2O was added dropwise, react.mixt. was stirred for 15 min, PPh3 was added, and mixt. allowed to warmto room temp. overnight; petrol (40-60) was added, ract. mixt. was filtered, ppt. was collected,extracted into THF, extracts were filtered, solvent was removed under reduced pressure; elem. anal.;

DOI:10.1021/om990385y

upstream raw materials:

iron pentacarbonyl

triphenylphosphine

trifluoroacetic anhydride

lithium diisopropyl amide