OsH(H₂)(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*CF₃SO₃^(1-)=OsH(H₂)(((C₆H₅)2PCH₂CH₂CH)2)(P(C₆H₅)3)CF₃SO₃

Base Information

• Chemical Name: OsH(H₂)(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*CF₃SO₃^(1-)=OsH(H₂)(((C₆H₅)2PCH₂CH₂CH)2)(P(C₆H₅)3)CF₃SO₃
• CAS No.: 474082-81-0
• Molecular Formula: CF₃O₃S*C₄₈H₄₈OsP₃
• Molecular Weight: 1057.1
• Mol file: 474082-81-0.mol

Synonyms:

Chemical Property of OsH(H₂)(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*CF₃SO₃^(1-)=OsH(H₂)(((C₆H₅)2PCH₂CH₂CH)2)(P(C₆H₅)3)CF₃SO₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of OsH(H₂)(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*CF₃SO₃^(1-)=OsH(H₂)(((C₆H₅)2PCH₂CH₂CH)2)(P(C₆H₅)3)CF₃SO₃

There total 3 articles about OsH(H₂)(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*CF₃SO₃^(1-)=OsH(H₂)(((C₆H₅)2PCH₂CH₂CH)2)(P(C₆H₅)3)CF₃SO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-[OsH2(PPh3)(Ph2PCH2CH2CHCHCH2CH2PPh2)*3H2O + trifluorormethanesulfonic acid (1493-13-6) → OsH(H2)(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2)(1+)*CF3SO3(1-)=OsH(H2)(((C6H5)2PCH2CH2CH)2)(P(C6H5)3)CF3SO3 (474082-81-0)

Guidance literature:

In dichloromethane-d2; under N2, room temp., 3 equiv. of triflic acid was added; detected by (1)H, (13)C and (31)P NMR immediately after mixing;

DOI:10.1002/1099-0682(200207)2002:7<1697::AID-EJIC1697>3.0.CO;2-O

Reference yield:

OsClH(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2) (474082-75-2) + hydrogen (1333-74-0) + thallium(I) triflate (73491-36-8) → OsH(H2)(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2)(1+)*CF3SO3(1-)=OsH(H2)(((C6H5)2PCH2CH2CH)2)(P(C6H5)3)CF3SO3 (474082-81-0)

Guidance literature:

In dichloromethane-d2; room temp., 3 equiv. of TlO3SCF3 was added, storage for 5 h under H2; detected by (1)H, (13)C and (31)P NMR;

DOI:10.1002/1099-0682(200207)2002:7<1697::AID-EJIC1697>3.0.CO;2-O

Reference yield:

OsCl(η(2)-H2)(PPh3)(Ph2PCH2CH2CHCHCH2CH2PPh2)CF3SO3 (474082-78-5) + hydrogen (1333-74-0) → OsCl(H)(x)(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2)(1+) + OsH(H2)(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2)(1+)*CF3SO3(1-)=OsH(H2)(((C6H5)2PCH2CH2CH)2)(P(C6H5)3)CF3SO3 (474082-81-0)

Guidance literature:

In dichloromethane-d2; room temp., storage for 18 h under H2; detected by (1)H, (13)C and (31)P NMR;

DOI:10.1002/1099-0682(200207)2002:7<1697::AID-EJIC1697>3.0.CO;2-O

upstream raw materials:

OsClH(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)

hydrogen

thallium(I) triflate

trifluorormethanesulfonic acid