Hexanoic acid trimethylsilyl ester

Base Information

• Chemical Name: Hexanoic acid trimethylsilyl ester
• CAS No.: 14246-15-2
• Molecular Formula: C9H20O2Si
• Molecular Weight: 188.342
• Hs Code.: 2931900090
• Mol file: 14246-15-2.mol

Synonyms:Hexansaeuretrimethylsilylester;Caproic acid,trimethylsilyl ester;hexanoic acid trimethylsilyl ester;

Chemical Property of Hexanoic acid trimethylsilyl ester

Chemical Property:

• PSA: 26.30000
• LogP: 2.94480

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hexanoic acid trimethylsilyl ester

There total 5 articles about Hexanoic acid trimethylsilyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

hexanoic acid (142-62-1) + allyl-trimethyl-silane (762-72-1) → propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + trimethylsilyl hexanoate (14246-15-2)

Guidance literature:

iodine; at 60 ℃; for 0.5h;

DOI:10.1246/cl.1981.85

Reference yield:

N,O-bis(trimethylsilyl)trifluoroacetamide (25561-30-2) + hexanoic acid (142-62-1) → 2,2,2-trifluoroacetamide (354-38-1) + trimethylsilyl hexanoate (14246-15-2) + N-(trimethylsilyl)trifluoroacetamide (55982-15-5)

Guidance literature:

In hexane; dichloromethane; at 60 ℃; for 0.666667h;

DOI:10.1021/es980129x

Reference yield:

1-trimethylsilanyloxy-hept-1-ene (17510-50-8) → trimethylsilyl hexanoate (14246-15-2) + hexanoic acid (142-62-1)

Guidance literature:

With tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI); In benzene; at 60 ℃; for 48h; Yield given. Yields of byproduct given;

DOI:10.1016/S0040-4039(01)90529-5

upstream raw materials:

trans-Crotonaldehyde

trimetylsilylketene

1-trimethylsilanyloxy-hept-1-ene

hexanoic acid

Downstream raw materials:

Hexamethyldisiloxane

3-(Triphenyl-λ⁵-phosphanylidene)-nonan-4-one

Trimethyl-{1-[2-phenyl-eth-(Z)-ylidene]-hexyloxy}-silane

hexanoic acid

Refernces

• 1、 Yu, Jianzhen,Flagan, Richard C.,Seinfeld, John H.. "Identification of products containing -COOH, -OH, and -C=O in atmospheric oxidation of hydrocarbons". . p. 2357 - 2370. Retrieved 2007/10/03.
• 2、 Hosomi, Akira,Sakurai, Hideki. "PROTECTION OF ALCOHOLS AND ACIDS WITH ALLYLSILANES CATALYZED BY IODINE OR IODOTRIMETHYLSILANE IN CHLORINATED HYDROCARBON". . p. 85 - 88. Retrieved 2007/10/02.