triethylammonium trans-dichloro[1,2-bis(2-pyridinecarboxamide)benzenato(-2)-η4-N(py),N(am),N(am),N(py)]vanadate(III)

Base Information

• Chemical Name: triethylammonium trans-dichloro[1,2-bis(2-pyridinecarboxamide)benzenato(-2)-η4-N(py),N(am),N(am),N(py)]vanadate(III)
• CAS No.: 188033-25-2
• Molecular Formula: C₆H₁₆N*C₁₈H₁₂Cl₂N₄O₂V
• Molecular Weight: 540.366
• Mol file: 188033-25-2.mol

Synonyms:

Chemical Property of triethylammonium trans-dichloro[1,2-bis(2-pyridinecarboxamide)benzenato(-2)-η4-N(py),N(am),N(am),N(py)]vanadate(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triethylammonium trans-dichloro[1,2-bis(2-pyridinecarboxamide)benzenato(-2)-η4-N(py),N(am),N(am),N(py)]vanadate(III)

There total 1 articles about triethylammonium trans-dichloro[1,2-bis(2-pyridinecarboxamide)benzenato(-2)-η4-N(py),N(am),N(am),N(py)]vanadate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

vanadium(III) chloride (7718-98-1) + N,N-bis(2-pyridinecarboxamide)-1,2-benzene (67455-94-1) + triethylamine (121-44-8) → triethylammonium trans-dichloro[1,2-bis(2-pyridinecarboxamide)benzenato(-2)-η4-N(py),N(am),N(am),N(py)]vanadate(III) (188033-25-2) + [VO(1,2-bis(2-pyridinecarboxamide)benzenato(-2))](x) (165620-25-7)

Guidance literature:

In toluene; byproducts: NH(C2H5)3Cl; (Ar); refluxed overnight; ppt. filtered off, washed (Et2O), dried (vac.), extd. (CH2Cl2), evapd.,dissolved in CHCl3, filtered, layered with Et2O at -20°C for 3 d, crystals filtered off, dried (vac.), sepd. manually under microscope; elem. anal.;

DOI:10.1021/ic990837z

upstream raw materials:

vanadium(III) chloride

N,N-bis(2-pyridinecarboxamide)-1,2-benzene

triethylamine