1-Butanone, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl-

Base Information

Chemical Name:1-Butanone, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl-
CAS No.:143878-47-1
Molecular Formula:C16H26O2Si
Molecular Weight:278.467
Hs Code.:
DSSTox Substance ID:DTXSID00453991
Nikkaji Number:J482.101G
Wikidata:Q82275300
Mol file:143878-47-1.mol

Synonyms:143878-47-1;1-Butanone, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl-;4-[tert-butyl(dimethyl)silyl]oxy-1-phenylbutan-1-one;4-((tert-Butyldimethylsilyl)oxy)-1-phenylbutan-1-one;4-[(TERT-BUTYLDIMETHYLSILYL)OXY]-1-PHENYLBUTAN-1-ONE;starbld0037073;SCHEMBL1928721;DTXSID00453991;BNWSUULROVPLEH-UHFFFAOYSA-N;EN300-399550;1-Phenyl-4-[(tert-butyldimethylsilyl)oxy]-1-butanone;4-(tert-butyldimethylsilanyloxv)-1-phenylbutan-1-one;4-(tert-butyldimethylsilanyloxy)-1-phenylbutan-1-one;4-{[tert-butyl(dimethyl)silyl]oxy}-1-phenylbutan-1-one

Suppliers and Price of 1-Butanone, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of 1-Butanone, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl-

Chemical Property:

PSA：26.30000
LogP:4.67130
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:278.170206602
Heavy Atom Count:19
Complexity:286

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OCCCC(=O)C1=CC=CC=C1

Technology Process of 1-Butanone, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl-

There total 4 articles about 1-Butanone, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 39755-03-8
4-hydroxy-1-phenyl-butan-1-one

: 18162-48-6
tert-butyldimethylsilyl chloride

: 143878-47-1
4-{[tert-butyl(dimethyl)silyl]oxy}-1-phenylbutan-1-one

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 14h;

Reference yield: 65.0%

: 108-86-1,52753-63-6
bromobenzene

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 89031-84-5
3-(tert-butyldimethylsilyloxy)propyl bromide

: 143878-47-1
4-{[tert-butyl(dimethyl)silyl]oxy}-1-phenylbutan-1-one

Guidance literature:: With (1,2-dimethoxyethane)dichloronickel(II); 4,4'-di-tert-butyl-2,2'-bipyridine; sodium iodide; zinc; In N,N-dimethyl acetamide; at 60 ℃; for 18h; Inert atmosphere;
DOI:10.1021/om5004682

Reference yield: 53.0%

: 143878-46-0
1-phenyl-1-trimethylsilyloxy-4-t-butyldimethylsilyloxybutane

: 39755-03-8
4-hydroxy-1-phenyl-butan-1-one

: 4850-50-4
1-phenyl-butane-1,4-diol

: 137333-75-6
4-tert-butyldimethylsilyloxy-1-phenylbutan-1-ol

: 143878-47-1
4-{[tert-butyl(dimethyl)silyl]oxy}-1-phenylbutan-1-one

Guidance literature:: With chromium(VI) oxide; tert.-butylhydroperoxide; triphenylhydroxysilane; In dichloromethane; for 20h; Product distribution; Ambient temperature; other secondary benzylic or allylic trimethylsilyl ethers, var. time;
DOI:10.1080/00397919208021332