3-allylphenol

Base Information

• Chemical Name: 3-allylphenol
• CAS No.: 1446-24-8
• Molecular Formula: C9H10O
• Molecular Weight: 134.178
• Hs Code.: 2909500090
• Mol file: 1446-24-8.mol

Synonyms:3-Allyl-phenol;m-Allylphenol;3-Hydroxy-1-allyl-benzol;

Chemical Property of 3-allylphenol

Chemical Property:

• Boiling Point: 108-115 °C(Press: 13 Torr)
• PKA: 9.99±0.10(Predicted)
• PSA: 20.23000
• Density: 1.014±0.06 g/cm3(Predicted)
• LogP: 2.12070

Purity/Quality:

99%, ^*data from raw suppliers

3-Allylphenol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-allylphenol

There total 9 articles about 3-allylphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-allyl-3-methoxybenzene (24743-14-4) → 3-allylphenol (1446-24-8)

Guidance literature:

1-allyl-3-methoxybenzene; With boron tribromide; In dichloromethane; at 0 ℃; for 3h;

With water; In dichloromethane;

Reference yield: 93.0%

1-Allyl-3-benzyloxy-benzene → 3-allylphenol (1446-24-8)

Guidance literature:

With pentamethylbenzene,; boron trichloride; In dichloromethane; at -78 ℃; for 0.333333h;

DOI:10.1055/S-2008-1077980

Reference yield: 49.0%

β-allyl-2-cyclohexenone (138832-46-9) → 3-allylphenol (1446-24-8)

Guidance literature:

With iodine; dimethyl sulfoxide; In nitromethane; at 100 ℃; for 24h; Sealed tube; Green chemistry;

DOI:10.1039/c6gc02674e

upstream raw materials:

1-(allyloxy)-3-bromobenzene

1-allyl-3-methoxybenzene

diethyl ether

4-allylguaiacol

Downstream raw materials:

1-allyl-3-methoxybenzene

3-allylphenyl acetate

C₁₈H₂₄O₅

(E)-3-(1-propen-1-yl)phenyl propionate

Refernces

• 1、 Liang, Yu-Feng,Song, Song,Ai, Lingsheng,Li, Xinwei,Jiao, Ning. "A highly efficient metal-free approach to: Meta - And multiple-substituted phenols via a simple oxidation of cyclohexenones". supporting information. p. 6462 - 6467. Retrieved 2018/06/08.
• 2、 Okano, Kentaro,Okuyama, Kei-Ichiro,Fukuyama, Tohru,Tokuyama, Hidetoshi. "Mild debenzylation of aryl benzyl ether with BCl3 in the presence of pentamethylbenzene as a non-lewis-basic cation scavenger". scheme or table. p. 1977 - 1980. Retrieved 2009/04/07.