(1S,2S)-cyclopropane-1,2-dicarboxylic acid

Base Information

Chemical Name:(1S,2S)-cyclopropane-1,2-dicarboxylic acid
CAS No.:14590-54-6
Molecular Formula:C₅H₆O₄
Molecular Weight:130.1
Hs Code.:2917209090
DSSTox Substance ID:DTXSID30426118
Nikkaji Number:J81.785F
Wikidata:Q82239084
Mol file:14590-54-6.mol

Synonyms:(1S,2S)-cyclopropane-1,2-dicarboxylic acid;14590-54-6;(1S,2S)-1,2-Cyclopropanedicarboxylic Acid;1,2-Cyclopropanedicarboxylic acid, (1S-trans)-;696-75-3;1,2-Cyclopropanedicarboxylic acid, (1S,2S)-;trans-1,2-Cyclopropanedicarboxylic acid;1,2-Cyclopropanedicarboxylic acid, trans-;MFCD00034639;SCHEMBL8495522;DTXSID30426118;MFCD06227617;AKOS016844193;1,2-Cyclopropanedicarboxylic acid, (E)-;1alpha,2beta-Cyclopropanedicarboxylic acid;AM807085;AS-49477;(1S,2S)-cyclopropane-1,2-dicarboxylicacid;CS-0053574;(S,S)-(+)-1,2-Cyclopropanedicarboxylic Acid;EN300-149790;I10810;P18271;(+)-(S)-1,2-trans-Cyclopropanedicarboxylic Acid;(+)-(1S, 2S)-Cyclopropane-1,2-dicarboxylic acid

Suppliers and Price of (1S,2S)-cyclopropane-1,2-dicarboxylic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(1S,2S)-1,2-CyclopropanedicarboxylicAcid
1g
$ 3065.00

Crysdot
(1S,2S)-Cyclopropane-1,2-dicarboxylicacid 95+%
1g
$ 675.00

Chemenu
(1S,2S)-cyclopropane-1,2-dicarboxylicacid 95%
1g
$ 631.00

Ambeed
(1S,2S)-Cyclopropane-1,2-dicarboxylicacid 95+%
5g
$ 1088.00

Ambeed
(1S,2S)-Cyclopropane-1,2-dicarboxylicacid 95+%
250mg
$ 120.00

Ambeed
(1S,2S)-Cyclopropane-1,2-dicarboxylicacid 95+%
1g
$ 311.00

AK Scientific
(1S,2S)-Cyclopropane-1,2-dicarboxylicacid
1g
$ 1197.00

AK Scientific
(1S,2S)-Cyclopropane-1,2-dicarboxylicacid
250mg
$ 517.00

ACHEMBLOCK
(1S,2S)-Rel-cyclopropane-1,2-dicarboxylicacid 97%
1G
$ 650.00

ACHEMBLOCK
(1S,2S)-Rel-cyclopropane-1,2-dicarboxylicacid 97%
250MG
$ 245.00

Total 17 raw suppliers

Chemical Property of (1S,2S)-cyclopropane-1,2-dicarboxylic acid

Chemical Property:

Melting Point:168-169 °C
Boiling Point:305.8±25.0 °C(Predicted)
PKA:3.84±0.11(Predicted)
PSA：74.60000
Density:1.673±0.06 g/cm3(Predicted)
LogP:-0.20830
Storage Temp.:2-8°C
Solubility.:DMSO (Slightly), Ethanol (Slightly)
XLogP3:-0.6
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:130.02660867
Heavy Atom Count:9
Complexity:144

Purity/Quality:

99%, ^*data from raw suppliers

(1S,2S)-1,2-CyclopropanedicarboxylicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C(C1C(=O)O)C(=O)O
Isomeric SMILES:C1[C@@H]([C@H]1C(=O)O)C(=O)O
General Description 1α,2β-Cyclopropanedicarboxylic acid is a highly optically active trans-1,2-cyclopropanedicarboxylic acid derivative, synthesized through asymmetric cyclopropanation of fumarates with methylene bromide using cobalt(0) or nickel(0) complexes as catalysts. The reaction yields enantiomerically enriched products, demonstrating the effectiveness of these metal complexes in facilitating stereoselective cyclopropane formation.

Technology Process of (1S,2S)-cyclopropane-1,2-dicarboxylic acid

There total 13 articles about (1S,2S)-cyclopropane-1,2-dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%