3,8-Dimethylacenaphthenequinone

Base Information

Chemical Name:3,8-Dimethylacenaphthenequinone
CAS No.:146885-81-6
Molecular Formula:C14H10O2
Molecular Weight:210.232
Hs Code.:
Mol file:146885-81-6.mol

Synonyms:acenaphthenequinone;3,8-dimethylacenaphthequinone;3,8-Dimethyl-acenaphthen-1,2-dion;3,8-dimethyl-acenaphthene-1,2-dione;3,8-dimethylacenaphthenequinone;2,7-Dimethylacenaphthenequinone;3,8-Dimethyl-acenaphthylene-1,2-dione;

Suppliers and Price of 3,8-Dimethylacenaphthenequinone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3,8-Dimethylacenaphthenequinone
100mg
$ 165.00

TCI Chemical
3,8-Dimethylacenaphthenequinone >97.0%(GC)
200mg
$ 128.00

TCI Chemical
3,8-Dimethylacenaphthenequinone >97.0%(GC)
1g
$ 382.00

AK Scientific
3,8-Dimethylacenaphthenequinone
200mg
$ 229.00

Total 7 raw suppliers

Chemical Property of 3,8-Dimethylacenaphthenequinone

Chemical Property:

Melting Point:204 - 205 °C
Boiling Point:408.2±35.0 °C(Predicted)
PSA：34.14000
Density:1.310±0.06 g/cm3(Predicted)
LogP:2.83560

Purity/Quality:

98%,99%, ^*data from raw suppliers

3,8-Dimethylacenaphthenequinone ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Uses 3,8-Dimethylacenaphthenequinone is a useful intermediate in the preparation of fluorinated and trifluoromethylated corannulenes.

Technology Process of 3,8-Dimethylacenaphthenequinone

There total 22 articles about 3,8-Dimethylacenaphthenequinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 56137-97-4
3,8-dimethyl-1-acenaphthenone

: 146885-81-6
3,8-dimethylacenaphthylene-1,2-dione

Guidance literature:: With selenium(IV) oxide; In 1,4-dioxane; water; at 60 ℃; for 48h;
DOI:10.1016/S0040-4039(00)60565-8

Reference yield: 53.0%

: 79-37-8
oxalyl dichloride

: 582-16-1
2,7-dimethylnaphthalene

: 146885-81-6
3,8-dimethylacenaphthylene-1,2-dione

: 4,7-dimethylacenaphthylene-1,2-dione

Guidance literature:: With aluminum tri-bromide; In dichloromethane; for 4h; cooling;
DOI:10.1021/jo071216n

Reference yield:

: 582-16-1
2,7-dimethylnaphthalene

: 146885-81-6
3,8-dimethylacenaphthylene-1,2-dione

Guidance literature:: Multi-step reaction with 5 steps

1: 62 percent / HCl; AcOH

2: 99 percent / acetone

3: 90 percent / H₂SO₄; AcOH

4: 82 percent / SOCl₂; AlCl₃ / CH₂Cl₂

5: 84 percent / SeO₂ / dioxane; H₂O

With hydrogenchloride; aluminium trichloride; selenium(IV) oxide; thionyl chloride; sulfuric acid; acetic acid; In 1,4-dioxane; dichloromethane; water; acetone;
DOI:10.1055/s-2003-44996