1,2-Ethenediylbis(trimethylsilane)

Base Information

• Chemical Name: 1,2-Ethenediylbis(trimethylsilane)
• CAS No.: 1473-61-6
• Molecular Formula: C₈H₂₀Si₂
• Molecular Weight: 172.418
• Mol file: 1473-61-6.mol

Synonyms:1,2-bis(trimethylsilyl)ethylene;1,2-Bis-(trimethylsilyl)-ethen;Bis-(trimethylsilyl)-ethylen;1,2-Bis-trimethylsilyl-ethylen;1,2-Bis-trimethylsilyl-aethylen;Silane,1,2-ethenediylbis[trimethyl;1,2-bis(trimethylsilyl)ethene;ethene-1,2-diylbis(trimethylsilane);

Chemical Property of 1,2-Ethenediylbis(trimethylsilane)

Chemical Property:

• PSA: 0.00000
• LogP: 3.29740

Purity/Quality:

99% ^*data from raw suppliers

1,2-BIS-(TRIMETHYLSILYL)ETHYLENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-Ethenediylbis(trimethylsilane)

There total 35 articles about 1,2-Ethenediylbis(trimethylsilane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Bis(trimethylsilyl)ethyne (14630-40-1) → (Z)-1,2-bis(trimethylsilyl)ethylene (1473-61-6,18178-59-1,34471-32-4,65450-95-5,87728-00-5,18178-60-4)

Guidance literature:

Bis(trimethylsilyl)ethyne; With titanium(IV) isopropylate; n-butyllithium; In tetrahydrofuran; hexane; at -78 - 50 ℃;

With hydrogen cation; In tetrahydrofuran; hexane; at 50 ℃; Further stages.;

DOI:10.1039/b310565b

Reference yield: 80.0%

diazomethyl-trimethyl-silane (18107-18-1) → 1,2-bis(trimethylsilyl)ethylene (1473-61-6,65450-95-5)

Guidance literature:

[Ru2(CO)4(μ-OAc)2]n; In dichloromethane; for 12h;

DOI:10.1016/S0040-4039(01)01221-7

Reference yield: 68.0%

ethyl vinyl ether (109-92-2,25104-37-4) + diazomethyl-trimethyl-silane (18107-18-1) → 1,2-bis(trimethylsilyl)ethylene (1473-61-6,65450-95-5) + (2-ethoxy-cyclopropyl)-trimethyl-silane

Guidance literature:

[Ru2(CO)4(μ-OAc)2]n; In dichloromethane; at -20 ℃;

DOI:10.1016/S0040-4039(01)01221-7

upstream raw materials:

chloro-trimethyl-silane

β-chlorovinyltrimethylsilane

trimethylsilylmethyllithium

trimethylsilan

Downstream raw materials:

(1,2-Bis-trimethylsilanyl-ethylsulfanyl)-benzene