Methyl(p-nitrophenylsulfonyl)acetate

Base Information

Chemical Name:Methyl(p-nitrophenylsulfonyl)acetate
CAS No.:14769-09-6
Molecular Formula:C9H9NO6S
Molecular Weight:259.24
Hs Code.:
DSSTox Substance ID:DTXSID80879776
Nikkaji Number:J696.267J
Wikidata:Q82861896
Mol file:14769-09-6.mol

Synonyms:Methyl(p-nitrophenylsulfonyl)acetate;14769-09-6;SCHEMBL17550644;DTXSID80879776;AKOS005830794;4-Nitrophenylsulfonyl-acetic acid, methyl ester

Suppliers and Price of Methyl(p-nitrophenylsulfonyl)acetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl(p-nitrophenylsulfonyl)acetate

Chemical Property:

XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:4
Exact Mass:259.01505818
Heavy Atom Count:17
Complexity:385

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)CS(=O)(=O)C1=CC=C(C=C1)[N+](=O)[O-]

Technology Process of Methyl(p-nitrophenylsulfonyl)acetate

There total 7 articles about Methyl(p-nitrophenylsulfonyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 6625-35-0
methyl 2-(4-nitrophenylsulfanyl)acetate

: 14769-09-6
methyl 2-((4-nitrophenyl)sulfonyl)acetate

Guidance literature:: With potassium peroxomonosulfate; In methanol; water; at 0 - 20 ℃;
DOI:10.1039/c0ob00852d

Reference yield: 72.0%

: 24067-17-2
4-nitrophenylboronic acid

: 96-32-2
bromoacetic acid methyl ester

: 14769-09-6
methyl 2-((4-nitrophenyl)sulfonyl)acetate

Guidance literature:: With tris(triphenylphosphine)ruthenium(II) chloride; 1,4-diazabicyclo [2.2.2] octane-1,4-diium-1,4-disulfinate; triethylamine; In methanol; at 100 ℃; for 8h; Sealed tube;
DOI:10.1021/acs.joc.9b03403

Reference yield:

: 1849-36-1
para-nitrobenzenethiol

: 14769-09-6
methyl 2-((4-nitrophenyl)sulfonyl)acetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 0.25 h / 0 °C

1.2: 20 °C

2.1: potassium peroxomonosulfate / methanol; water / 0 - 20 °C

With potassium peroxomonosulfate; potassium carbonate; In methanol; water; N,N-dimethyl-formamide;
DOI:10.1039/c0ob00852d