9H-Carbazole, 3-methoxy-9-methyl-

Base Information

• Chemical Name: 9H-Carbazole, 3-methoxy-9-methyl-
• CAS No.: 152404-99-4
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.263
• Mol file: 152404-99-4.mol

Synonyms:

Chemical Property of 9H-Carbazole, 3-methoxy-9-methyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9H-Carbazole, 3-methoxy-9-methyl-

There total 2 articles about 9H-Carbazole, 3-methoxy-9-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2-iodo-N-(4-methoxyphenyl)-N-methylaniline → 3-methoxy-9-methyl-9H-carbazole (152404-99-4) + N-(4-methoxyphenyl)-N-methylaniline (55251-46-2)

Guidance literature:

With potassium tert-butylate; ethylene glycol; In dimethyl sulfoxide; at 30 ℃; for 12h; Reagent/catalyst; Inert atmosphere; Green chemistry;

DOI:10.1002/ejoc.201601293

Reference yield:

C13H12INO (1222360-33-9) → 3-methoxy-9-methyl-9H-carbazole (152404-99-4) + N-(4-methoxyphenyl)-N-methylaniline (55251-46-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: acetic acid / water; acetonitrile / 3 h / 20 °C

1.2: 0 - 20 °C

2.1: potassium tert-butylate; ethylene glycol / dimethyl sulfoxide / 12 h / 30 °C / Inert atmosphere; Green chemistry

With potassium tert-butylate; ethylene glycol; acetic acid; In water; dimethyl sulfoxide; acetonitrile;

DOI:10.1002/ejoc.201601293

Reference yield:

3-methoxy-9-methyl-9H-carbazole (152404-99-4) → 3-hydroxy-9-methylcarbazole (52602-27-4)

Guidance literature:

upstream raw materials:

C₁₃H₁₂INO

Downstream raw materials:

3-hydroxy-9-methylcarbazole