Benzene, 1-bromo-2-[[3-(2-propenyloxy)phenyl]thio]-

Base Information

Chemical Name:Benzene, 1-bromo-2-[[3-(2-propenyloxy)phenyl]thio]-
CAS No.:152610-18-9
Molecular Formula:C15H13BrOS
Molecular Weight:321.238
Hs Code.:
Mol file:152610-18-9.mol

Synonyms:

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Chemical Property of Benzene, 1-bromo-2-[[3-(2-propenyloxy)phenyl]thio]-

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Technology Process of Benzene, 1-bromo-2-[[3-(2-propenyloxy)phenyl]thio]-

There total 1 articles about Benzene, 1-bromo-2-[[3-(2-propenyloxy)phenyl]thio]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 71112-91-9
bis(2-bromophenyl) disulfide

: 41388-50-5
1-(allyloxy)-3-bromobenzene

: 152610-18-9
2-<3-(allyloxy)thiophenoxy>bromobenzene

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction; 1.) THF, -74 deg C, 30 min, 2.) THF, from -74 deg C to RT;
DOI:10.1021/jm00022a006

Reference yield:

: 152610-18-9
2-<3-(allyloxy)thiophenoxy>bromobenzene

: 2-{3-[3-(5-Ethyl-4'-fluoro-2-hydroxy-biphenyl-4-yloxy)-propoxy]-2-propyl-benzenesulfonyl}-benzoic acid

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) n-BuLi / 1.) THF, -78 deg C, 15 min, 2.) THF, from -78 deg C to RT

2: HCl(g) / 18 h / Ambient temperature

3: 41 percent / 30 h / 175 °C

4: 66 percent / K₂CO₃, KI, DMSO / butan-2-one / 18 h / Heating

5: H₂ / 10percent Pd/C / ethyl acetate / 760 Torr / Ambient temperature

6: BBr₃ / CH₂Cl₂ / 1 h / -78 °C

7: 100 percent / aq. NaOH / methanol; tetrahydrofuran / 1 h / Ambient temperature

8: 58 percent / 85percent m-chloroperoxybenzoic acid / CH₂Cl₂ / 19 h / 0 - 4 °C

With hydrogenchloride; sodium hydroxide; n-butyllithium; hydrogen; boron tribromide; potassium carbonate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; potassium iodide; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; butanone;
DOI:10.1021/jm00022a006

Reference yield:

: 152610-18-9
2-<3-(allyloxy)thiophenoxy>bromobenzene

: 152608-55-4
2-[2-propyl-3-[3-[2-ethyl-4-(4-fluorophenyl)-5-hydroxyphenoxy]propoxy]phenylsulfinyl]-benzoic acid

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) n-BuLi / 1.) THF, -78 deg C, 15 min, 2.) THF, from -78 deg C to RT

2: HCl(g) / 18 h / Ambient temperature

3: 41 percent / 30 h / 175 °C

4: 66 percent / K₂CO₃, KI, DMSO / butan-2-one / 18 h / Heating

5: H₂ / 10percent Pd/C / ethyl acetate / 760 Torr / Ambient temperature

6: BBr₃ / CH₂Cl₂ / 1 h / -78 °C

7: 100 percent / aq. NaOH / methanol; tetrahydrofuran / 1 h / Ambient temperature

8: 80 percent / 85percent m-chloroperoxybenzoic acid / CH₂Cl₂ / 0.67 h / -78 °C

With hydrogenchloride; sodium hydroxide; n-butyllithium; hydrogen; boron tribromide; potassium carbonate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; potassium iodide; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; butanone;
DOI:10.1021/jm00022a006