Benzene, (2Z)-2-butenyl-

Base Information

• Chemical Name: Benzene, (2Z)-2-butenyl-
• CAS No.: 15324-90-0
• Molecular Formula: C10H12
• Molecular Weight: 132.205
• Mol file: 15324-90-0.mol

Synonyms:

Chemical Property of Benzene, (2Z)-2-butenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzene, (2Z)-2-butenyl-

There total 58 articles about Benzene, (2Z)-2-butenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-bromo-2,3-epoxy-4-phenylbutane (511553-23-4) → (2Z)-but-2-en-1-ylbenzene (15324-90-0)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane; phosphorous acid trimethyl ester; In benzene; Heating;

DOI:10.1021/ja020761x

Reference yield: 80.0%

3-benzyl-4-(bromomethyl)oxetan-2-one (125763-09-9) → trans-4-phenyl-2-butene (935-00-2) + 4-Phenylbut-1-ene (768-56-9) + (2Z)-but-2-en-1-ylbenzene (15324-90-0) + rac-(3R,4R)-3-benzyl-4-methyloxetan-2-one

Guidance literature:

With diphenyl diselenide; tri-n-butyl-tin hydride; In benzene; for 4h; Title compound not separated from byproducts; Ambient temperature;

DOI:10.1021/ja980447w

Reference yield: 77.0%

4-phenylbutan-2-yl pyridine-2-sulfonate + methylmagnesium chloride (676-58-4) → trans-4-phenyl-2-butene (935-00-2) + (3-methylbutyl)benzene (2049-94-7) + (2Z)-but-2-en-1-ylbenzene (15324-90-0)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In tetrahydrofuran; at 0 ℃; for 0.5h; stereoselective reaction;

DOI:10.1021/acs.orglett.9b00976

upstream raw materials:

(E)-but-2-enol

2-hydroxy-3-butene

trans-but-2-enyl chloride

1-methyl-3-phenylallene

Downstream raw materials:

(E)-4-Phenyl-but-3-en-2-yl-hydroperoxide

trans-4-phenyl-2-butene

trans-1-phenyl-1-butene

Refernces

• 1、 Hayashi, Tamio,Konishi, Mitsuo,Yokota, Kan-ichi,Kumada, Makoto. "Regioselective Allylation of a Grignard Reagent Catalysed by Phosphine-Nickel and -Palladium Complexes". . p. 313 - 314. Retrieved 1981.
• 2、 Felkin,Swierczewski. "-". . p. 1433. Retrieved 1972.
• 3、 Chang, Alison Sy-Min,Cook, Amanda K.,Kawamura, Kiana E.,Martin, Daryl J.,Morris, Parker T.,Smith, Haley M.. "Modular Ni(0)/Silane Catalytic System for the Isomerization of Alkenes". . p. 486 - 496. Retrieved 2022/03/02.
• 4、 Pang, Xiaobo,Zhao, Zhen-Zhen,Wei, Xiao-Xue,Qi, Liangliang,Xu, Guang-Li,Duan, Jicheng,Liu, Xue-Yuan,Shu, Xing-Zhong. "Regiocontrolled Reductive Vinylation of Aliphatic 1,3-Dienes with Vinyl Triflates by Nickel Catalysis". supporting information. p. 4536 - 4542. Retrieved 2021/04/07.