2-(Diphenylphosphino)benzaldehyde oxime

Base Information

• Chemical Name: 2-(Diphenylphosphino)benzaldehyde oxime
• CAS No.: 153358-05-5
• Molecular Formula: C19H16NOP
• Molecular Weight: 305.31000
• Hs Code.: 2931900090
• European Community (EC) Number: 681-472-0
• Mol file: 153358-05-5.mol

Synonyms:2-(Diphenylphosphino)benzaldehyde oxime;153358-05-5;(NE)-N-[(2-diphenylphosphanylphenyl)methylidene]hydroxylamine;SCHEMBL7902396

Chemical Property of 2-(Diphenylphosphino)benzaldehyde oxime

Chemical Property:

• Melting Point: 173-178°C
• Boiling Point: 433.9±28.0 °C(Predicted)
• PKA: 10.62±0.10(Predicted)
• PSA: 46.18000
• LogP: 3.25290
• Water Solubility.: Insoluble in water.
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 305.096951132
• Heavy Atom Count: 22
• Complexity: 329

Purity/Quality:

99% ^*data from raw suppliers

2-(Diphenylphosphino)benzaldehyde oxime 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3C=NO
• Isomeric SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3/C=N/O
• Uses: It is used in the synthesis, structure and applications to the catalytic rearrangement and dehydration of aldoximes.

Technology Process of 2-(Diphenylphosphino)benzaldehyde oxime

There total 1 articles about 2-(Diphenylphosphino)benzaldehyde oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(2-formylphenyl)(diphenyl)phosphine (50777-76-9) → 2-(diphenylphosphanyl)benzaldehyde oxime (153358-05-5)

Guidance literature:

With hydroxylamine hydrochloride; sodium hydrogencarbonate; In ethanol; water; for 2h; Ambient temperature;

Reference yield: 87.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 2-(diphenylphosphanyl)benzaldehyde oxime (153358-05-5) → [PtCl2{κ2-(P,N)-2-Ph2PC6H4CH=NOH}]

Guidance literature:

In dichloromethane; at 20 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201800398

Reference yield: 85.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + 2-(diphenylphosphanyl)benzaldehyde oxime (153358-05-5) + nickel dichloride (83864-14-6) → [Ni(Ph2PC6H4-2-CH=NOH)Cl2]2*0.5THF

Guidance literature:

at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/c8dt01551a

upstream raw materials:

(2-formylphenyl)(diphenyl)phosphine

Refernces

• 1、 Nikitidis, Antonios,Andersson, Carlaxel. "POLYMERIZABLE DERIVATIVES OF TRIPHENYLPHOSPHINE. ACYLATION OF TRIARYLPHOSPHINES BEARING ALCOHOL OR AMINE SUBSTITUENTS WITH ACRYLOYLCHLORIDE AND METHACRYLOYLCHLORIDE". . p. 141 - 152. Retrieved 2007/10/02.