(1,5-Cyclohexadienyl)benzene

Base Information

• Chemical Name: (1,5-Cyclohexadienyl)benzene
• CAS No.: 15619-34-8
• Molecular Formula: C12H12
• Molecular Weight: 156.227
• Hs Code.: 2902909090
• Mol file: 15619-34-8.mol

Synonyms:Benzene,1,5-cyclohexadien-1-yl;3,4-dihydro-1,10-biphenyl;1-(cyclohexa-1,5-dienyl)benzene;2-phenylcyclohexa-1,3-diene;2-Phenyl-cyclohexa-1,3-dien;3,4-dihydrobiphenyl;2-phenyl-1,3-cyclohexadiene;

Chemical Property of (1,5-Cyclohexadienyl)benzene

Chemical Property:

• PSA: 0.00000
• LogP: 3.42000

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1,5-Cyclohexadienyl)benzene

There total 22 articles about (1,5-Cyclohexadienyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

cyclohexa-2,4-dienyl trifluoromethanesulfonate (63028-10-4) + phenylmagnesium bromide (100-58-3) → 1-(cyclohexa-1,5-dienyl)benzene (15619-34-8)

Guidance literature:

With copper(l) iodide; In tetrahydrofuran; at 0 ℃;

DOI:10.1021/jo971737i

Reference yield: 78.2%

3-phenyl-cyclohex-2-enol (17488-64-1) → 1-(cyclohexa-1,5-dienyl)benzene (15619-34-8)

Guidance literature:

With 2,4-dinitrobenzenesulfenyl chloride; triethylamine; In 1,2-dichloro-ethane; for 2.5h; Heating;

DOI:10.1021/jo00115a012

Reference yield: 77.0%

2-phenylcyclohex-2-enol (32363-86-3) → 1-(cyclohexa-1,5-dienyl)benzene (15619-34-8)

Guidance literature:

With 2,4-dinitrobenzenesulfenyl chloride; triethylamine; In 1,2-dichloro-ethane; for 3h; Heating;

DOI:10.1021/ja00389a028

upstream raw materials:

1,4-bis(triphenylphosphorylidene)butane

phenylglyoxal hydrate

2-phenylcyclohex-2-enol

3-phenyl-cyclohex-2-enol

Downstream raw materials:

1-Phenylcyclohexene

(2S,6R,7R)-8-Phenyl-4-oxa-tricyclo[5.2.2.0^2,6]undec-8-ene-3,5-dione

4,8-Diphenyl-2,4,6-triaza-tricyclo[5.2.2.0^2,6]undec-8-ene-3,5-dione

biphenyl