32363-86-3

Basic information

• Product Name: 2-Cyclohexen-1-ol, 2-phenyl-
• CAS NO: 32363-86-3
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 32363-86-3.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-ol, 2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-ol, 2-phenyl-(32363-86-3)
• EPA Substance Registry System: 2-Cyclohexen-1-ol, 2-phenyl-(32363-86-3)

Safety Data

• Hazardous Substances Data: 32363-86-3(Hazardous Substances Data)

Upstream product

• 71445-66-4 2-phenylcyclohexanone benzenesulfonylhydrazone 
• 5775-23-5 1-phenylcyclohexene oxide 
• 61077-30-3 2-phenyl-2cyclohexenyl hydroperoxide 
• 771-98-2 1-Phenylcyclohexene 
• 1444-65-1 (RS)-2-phenylcyclohexanone 
• 4556-09-6 2-phenylcyclohex-2-enone 
• 40940-64-5 (±)-6-bromo-1-phenylcyclohex-1-ene 
• 67-56-1 methanol 
• 71445-65-3 1-phenyl-3-(trimethylsilyl)cyclohex-1-ene 
• 33948-36-6 2-iodocyclohex-2-en-1-one 
• 930-68-7 cyclohexenone 

Downstream Products

• 335639-96-8 methyl 2-phenyl-2-cyclohexenyl carbonate 
• 2362-61-0 cis-2-phenylcyclohexanol 
• 488711-03-1 2,3,4,5-tetrahydro-[1,1'-biphenyl]-2-yl benzoate 
• 1444-65-1 (RS)-2-phenylcyclohexanone 
• 2362-61-0 trans-2-Phenylcyclohexanol 
• 109379-98-8 (R)-(+)-2-phenyl-cyclohex-2-en-1-ol 

Relevant articles and documents

Visible-Light Photoredox Catalyzed Dehydrogenative Synthesis of Allylic Carboxylates from Styrenes

The visible-light photoredox/[Co(III)] cocatalyzed dehydrogenative functionalization of cyclic and acyclic styryl derivatives with carboxylic acids is documented. The methodology enables the chemo- and regioselective allylic functionalization of styryl compounds, leading to allylic carboxylates (32 examples) under stoichiometric acceptorless conditions. Intermolecular as well as intramolecular variants are documented in high yields (up to 82%). A mechanistic rationale is also proposed on the basis of a combined experimental and spectroscopic investigation.

Are bis(pyridine)iodine(i) complexes applicable for asymmetric halogenation?

Enantiopure halogenated molecules are of tremendous importance as synthetic intermediates in the construction of pharmaceuticals, fragrances, flavours, natural products, pesticides, and functional materials. Enantioselective halofunctionalizations remain

Syn-dihydroxylation of alkenes using a sterically demanding cyclic diacyl peroxide

The syn-dihydroxylation of alkenes is a highly valuable reaction in organic synthesis. Cyclic acyl peroxides (CAPs) have emerged recently as promising candidates to replace the commonly employed toxic metals for this purpose. Here, we demonstrate that the structurally demanding cyclic peroxide spiro[bicyclo[2.2.1]heptane-2,4′-[1,2]dioxolane]-3′,5′-dione (P4) can be effectively used for the syn-dihydroxylation of alkenes. Reagent P4 also shows an improved selectivity for dihydroxylation of alkenes bearing β-hydrogens as compared to other CAPs, where both diol and allyl alcohol products compete with each other. Furthermore, the use of enantiopure P4 (labeled P4′) demonstrates the potential of P4′ for a metal-free asymmetric syn-dihydroxylation of alkenes.