7-Octenoic acid methyl ester

Base Information

• Chemical Name: 7-Octenoic acid methyl ester
• CAS No.: 15766-90-2
• Molecular Formula: C9H16O2
• Molecular Weight: 156.225
• Mol file: 15766-90-2.mol

Synonyms:methyl octa-7-enoate;methyl oct-7-enoate;methyl 7-octenoate;Oct-7-ensaeure-methylester;

Chemical Property of 7-Octenoic acid methyl ester

Chemical Property:

• PSA: 26.30000
• LogP: 2.29590

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 7-Octenoic acid methyl ester

There total 1 articles about 7-Octenoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

azelaic monomethyl ester (2104-19-0) → methyl octanate (111-11-5) + oct-7-enoic acid methyl ester (15766-90-2) + dimethyl hexadecanedioate (19102-90-0)

Guidance literature:

With potassium hydroxide; In methanol; at 45 ℃; Yield given; electrolysis: anode: platinum foil; current source: galvanostat; current density 220 mA cm^-2; current consumption: 1.4 F mol^-1; cell voltage 20 V;

DOI:10.3891/acta.chem.scand.52-0672

Reference yield: 76.0%

oct-7-enoic acid methyl ester (15766-90-2) + 4-nitro-benzoic acid (62-23-7) → 8-methoxy-8-oxooct-1-en-3-yl 4-nitrobenzoate

Guidance literature:

With [1,2-bis-(phenylsulfinyl)ethane]palladium(II) acetate; silver carbonate; p-benzoquinone; In 1,4-dioxane; at 45 ℃; for 24h;

DOI:10.1021/acs.orglett.1c02406

Reference yield: 75.0%

4-bromophenyl-4-butylphenyl methanone (91404-25-0) + oct-7-enoic acid methyl ester (15766-90-2) → 8-<4-(4-n-butylbenzoyl)phenyl>octanoic acid methyl ester (147299-38-5)

Guidance literature:

oct-7-enoic acid methyl ester; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 20 ℃; for 4h;

4-bromophenyl-4-butylphenyl methanone; With triphenyl-arsane; caesium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; water; N,N-dimethyl-formamide; Heating;

DOI:10.1021/jo061617n

upstream raw materials:

azelaic monomethyl ester

Downstream raw materials:

methyl hept-6-ynoate

oct-7-en-1-ol

8-<4-(4-n-butylbenzoyl)phenyl>octanoic acid methyl ester

8-<4-(4-n-butylbenzoyl)phenyl>octanoic acid

Refernces