9,10-Dibromophenanthrene

Base Information

• Chemical Name: 9,10-Dibromophenanthrene
• CAS No.: 15810-15-8
• Molecular Formula: C14H8Br2
• Molecular Weight: 336.026
• European Community (EC) Number: 659-647-8
• DSSTox Substance ID: DTXSID10399891
• Nikkaji Number: J81.885B
• Mol file: 15810-15-8.mol

Synonyms:9,10-dibromophenanthrene;15810-15-8;Phenanthrene, 9,10-dibromo-;9,10-Dibromo-phenanthrene;MFCD00092256;9.10-Phenanthren-dibromid;YSWG302;SCHEMBL12627623;DTXSID10399891;AKOS022172157;AS-76804;SY279393;CS-0129688;FT-0742552;E78786;A853650

Chemical Property of 9,10-Dibromophenanthrene

Chemical Property:

• Melting Point: 179-180℃ (heptane )
• Boiling Point: 441.1±18.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.768±0.06 g/cm3 (20 oC 760 Torr)
• LogP: 5.51800
• Storage Temp.: 2-8°C
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 335.89723
• Heavy Atom Count: 16
• Complexity: 227

Purity/Quality:

98% ^*data from raw suppliers

9,10-DIBROMOPHENANTHRENE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3C(=C2Br)Br

Technology Process of 9,10-Dibromophenanthrene

There total 9 articles about 9,10-Dibromophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2,2′‐bis(dibromomethyl)‐1,1′‐biphenyl (92161-37-0) → 9,10‐dibromophenanthrene (15810-15-8)

Guidance literature:

With potassium tert-butylate; In N,N-dimethyl-formamide; at 0 ℃; for 1h;

DOI:10.3390/molecules25020322

Reference yield:

phenanthrene (85-01-8) → 9,10‐dibromophenanthrene (15810-15-8)

Guidance literature:

With bromine; sodium bromide; In acetic acid;

DOI:10.1021/ja00976a027

Reference yield:

9,10-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenanthrene (1091603-62-1) → 9,10‐dibromophenanthrene (15810-15-8)

Guidance literature:

With copper(ll) bromide; In methanol; water; ethyl acetate; at 130 ℃; for 4h; Inert atmosphere;

DOI:10.1039/c8dt04820g

upstream raw materials:

9-Bromo-10-nitrophenanthrene

phenanthrene

phenanthro[9,10-d][1,2,3]triazol-1-ylamine

9,10-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenanthrene

Downstream raw materials:

9,10-bis(trimethylsilyl)phenanthrene

Refernces

• 1、 Chum,Henry. "". . p. 150. Retrieved 1976.