1,2,3,4,4a,9,10,10a-octahydrophenanthrene

Base Information

• Chemical Name: 1,2,3,4,4a,9,10,10a-octahydrophenanthrene
• CAS No.: 16306-39-1
• Molecular Formula: C14H18
• Molecular Weight: 186.297
• Mol file: 16306-39-1.mol

Synonyms:1,2,3,4,4a,9,10,10a-octahydro-phenanthrene;Phenanthrene,1,2,3,4,4a,9,10,10a-octahydro;unsym-Octahydrophenanthrene;cis and trans-1,2,3,4,4a,9,10,10a-Octahydrophenanthrenes;(+-)-cis-1,2,3,4,4a,9,10,10a-octahydro-phenanthrene;cis-as-Octahydrophenanthren;1,2,3,4,4a,9,10,10a-Octahydrophenanthrene (trans);(+-)-cis-1,2,3,4,4a,9,10,10a-Octahydro-phenanthren;Phenanthrene, 1,2,3,4,4a,9,10,10a-octahydro-;1,2,3,4,4a,9,10,10a-Octahydrophenanthrene (cis);

Chemical Property of 1,2,3,4,4a,9,10,10a-octahydrophenanthrene

Chemical Property:

• Vapor Pressure: 0.00373mmHg at 25°C
• Refractive Index: 1.5527
• Boiling Point: 289.8oC at 760 mmHg
• Flash Point: 131.7oC
• PSA: 0.00000
• Density: 0.989g/cm3
• LogP: 3.90660

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2,3,4,4a,9,10,10a-octahydrophenanthrene

There total 35 articles about 1,2,3,4,4a,9,10,10a-octahydrophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

9,10-dihydrophenanthrene (776-35-2) → 1,2,3,4,4a,9,10,10a-octahydrophenanthrene (16306-39-1) + 1,2,3,4-tetrahydrophenanthrene (1013-08-7) + 1,2,3,4,5,6,7,8-Octahydrophenanthrene (5325-97-3)

Guidance literature:

With hydrogen; nickel; In water; ethylene glycol; at 80 ℃; Product distribution; 0.1M NaCl, 0.1M H₃BO₃, pH 2.6-2.7 to 6.0-6.4;

Reference yield: 36.4%

phenanthrene (85-01-8) → 1,2,3,4,4a,9,10,10a-octahydrophenanthrene (16306-39-1) + 9,10-dihydrophenanthrene (776-35-2) + 1,2,3,4,9,10-hexahydrophenanthrene (16896-36-9) + 1,2,3,4,5,6,7,8-Octahydrophenanthrene (5325-97-3)

Guidance literature:

With hydrogen; lithium aluminium tetrahydride; titanium tetrachloride; In n-heptane; at 200 ℃; for 10h; under 67505.4 Torr; Product distribution; other conditions: other solvent (diglyme), other times, other catalysts;;

Reference yield: 4.0%

phenanthrene (85-01-8) → 1,2,3,4,4a,9,10,10a-octahydrophenanthrene (16306-39-1) + 9,10-dihydrophenanthrene (776-35-2) + 1,2,3,4-tetrahydrophenanthrene (1013-08-7) + 1,2,3,4,5,6,7,8-Octahydrophenanthrene (5325-97-3)

Guidance literature:

With hydrogen; nickel; In water; ethylene glycol; at 80 ℃; Product distribution; 0.1M NaCl, 0.05M H₃BO₃, pH 2.7 to 10.4; also in different solvents with various supporting electrolytes, at various temperatures and current densities; influence of pH and buffer;

upstream raw materials:

phenanthrene

9,10-dihydrophenanthrene

1,2,3,4-tetrahydrophenanthrene

8,9-trans-6-<2-(dimethylamino)-1(R)-phenylethoxy>octahydrophenanthrene

Downstream raw materials:

9,10-dihydrophenanthrene

cis-1,2,3,4,4a,9,10,10a-octahydrophenanthren-9-one

trans-1,2,3,4,4a,10a-hexahydro-9(10H)-phenanthrenone

phenanthrene