(3-Methoxy-3-phenylpenta-1,4-diyn-1-yl)(trimethyl)silane

Base Information

Chemical Name:(3-Methoxy-3-phenylpenta-1,4-diyn-1-yl)(trimethyl)silane
CAS No.:165055-35-6
Molecular Formula:C15H18OSi
Molecular Weight:242.393
Hs Code.:
DSSTox Substance ID:DTXSID40572094
Nikkaji Number:J2.104.692B
Mol file:165055-35-6.mol

Synonyms:165055-35-6;(3-Methoxy-3-phenylpenta-1,4-diyn-1-yl)(trimethyl)silane;DTXSID40572094

Suppliers and Price of (3-Methoxy-3-phenylpenta-1,4-diyn-1-yl)(trimethyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3-Methoxy-3-phenylpenta-1,4-diyn-1-yl)(trimethyl)silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:242.112691728
Heavy Atom Count:17
Complexity:364

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(C#C)(C#C[Si](C)(C)C)C1=CC=CC=C1

Technology Process of (3-Methoxy-3-phenylpenta-1,4-diyn-1-yl)(trimethyl)silane

There total 5 articles about (3-Methoxy-3-phenylpenta-1,4-diyn-1-yl)(trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 99048-51-8
3-phenyl-1-(trimethylsilyl)penta-1,4-diyn-3-ol

: 74-88-4
methyl iodide

: 165055-35-6
1-trimethylsilyl-3-phenyl-3-methoxypenta-1,4-diyne

Guidance literature:: 3-phenyl-1-(trimethylsilyl)penta-1,4-diyn-3-ol; With n-butyllithium; In tetrahydrofuran; at -78 ℃; Schlenk technique; Inert atmosphere;

methyl iodide; In dimethyl sulfoxide; at -25 ℃; Schlenk technique; Inert atmosphere;
DOI:10.1039/c7nj00028f

Reference yield:

: 13829-77-1
3-(trimethylsilyl)-1-phenyl-2-propyn-1-one

: 165055-35-6
1-trimethylsilyl-3-phenyl-3-methoxypenta-1,4-diyne

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / EtMgBr / tetrahydrofuran; diethyl ether / 20 °C

2: 83 percent / n-BuLi / tetrahydrofuran; hexane; dimethylsulfoxide / -20 - 20 °C

With n-butyllithium; ethylmagnesium bromide; In tetrahydrofuran; diethyl ether; hexane; dimethyl sulfoxide;
DOI:10.1016/j.tet.2004.07.052

Reference yield:

: 14630-40-1
Bis(trimethylsilyl)ethyne

: 165055-35-6
1-trimethylsilyl-3-phenyl-3-methoxypenta-1,4-diyne

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / AlCl₃ / CH₂Cl₂ / 20 °C

2: 93 percent / EtMgBr / tetrahydrofuran; diethyl ether / 20 °C

3: 83 percent / n-BuLi / tetrahydrofuran; hexane; dimethylsulfoxide / -20 - 20 °C

With n-butyllithium; aluminium trichloride; ethylmagnesium bromide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; dimethyl sulfoxide;
DOI:10.1016/j.tet.2004.07.052